Shape-Morphing Nanocomposite Origami
Nature provides a vast array of solid materials that repeatedly and reversibly transform in shape in response to environmental variations. This property is essential, for example, for new energy-saving technologies, efficient collection of solar radiation, and thermal management. Here we report a si...
Gespeichert in:
Veröffentlicht in: | Langmuir 2014-05, Vol.30 (19), p.5378-5385 |
---|---|
Hauptverfasser: | , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
container_end_page | 5385 |
---|---|
container_issue | 19 |
container_start_page | 5378 |
container_title | Langmuir |
container_volume | 30 |
creator | Andres, Christine M Zhu, Jian Shyu, Terry Flynn, Connor Kotov, Nicholas A |
description | Nature provides a vast array of solid materials that repeatedly and reversibly transform in shape in response to environmental variations. This property is essential, for example, for new energy-saving technologies, efficient collection of solar radiation, and thermal management. Here we report a similar shape-morphing mechanism using differential swelling of hydrophilic polyelectrolyte multilayer inkjets deposited on an LBL carbon nanotube (CNT) composite. The out-of-plane deflection can be precisely controlled, as predicted by theoretical analysis. We also demonstrate a controlled and stimuli-responsive twisting motion on a spiral-shaped LBL nanocomposite. By mimicking the motions achieved in nature, this method offers new opportunities for the design and fabrication of functional stimuli-responsive shape-morphing nanoscale and microscale structures for a variety of applications. |
doi_str_mv | 10.1021/la404955s |
format | Article |
fullrecord | <record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_4049491</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2000572030</sourcerecordid><originalsourceid>FETCH-LOGICAL-a465t-f36c0d8030b035010c2acabc0923dcc404559cc9ddfc68c95ab38a0053edc8ed3</originalsourceid><addsrcrecordid>eNptkF1LwzAYhYMobk4v_AMyREEvqm-apk1uBBl-gR8X6nXI3mZbRtvUpBX890amQ8GrQPJwcs5DyD6FMwopPa90BpnkPGyQIeUpJFykxSYZQpGxpMhyNiA7ISwBQLJMbpNBmuVCShBDcvS80K1JHpxvF7aZjx9149DVrQu2M-Mnb-e6trtka6arYPa-zxF5vb56mdwm9083d5PL-0RnOe-SGcsRSgEMpsA4UMBUo54iyJSViLEj5xJRluUMc4GS6ykTGoAzU6IwJRuRi1Vu20_reGeazutKtd7W2n8op636-9LYhZq7d_U1P5M0BhyuAlzorAoYN-ACXdMY7BSleSGEiNDJ9y_evfUmdKq2AU1V6ca4Pqg0euJFGmdE9HSFoncheDNbd6GgvtSrtfrIHvwuvyZ_XEfgeAVoDGrpet9El_8EfQJPNIpZ</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2000572030</pqid></control><display><type>article</type><title>Shape-Morphing Nanocomposite Origami</title><source>MEDLINE</source><source>ACS Publications</source><creator>Andres, Christine M ; Zhu, Jian ; Shyu, Terry ; Flynn, Connor ; Kotov, Nicholas A</creator><creatorcontrib>Andres, Christine M ; Zhu, Jian ; Shyu, Terry ; Flynn, Connor ; Kotov, Nicholas A ; Energy Frontier Research Centers (EFRC) ; Center for Solar and Thermal Energy Conversion (CSTEC)</creatorcontrib><description>Nature provides a vast array of solid materials that repeatedly and reversibly transform in shape in response to environmental variations. This property is essential, for example, for new energy-saving technologies, efficient collection of solar radiation, and thermal management. Here we report a similar shape-morphing mechanism using differential swelling of hydrophilic polyelectrolyte multilayer inkjets deposited on an LBL carbon nanotube (CNT) composite. The out-of-plane deflection can be precisely controlled, as predicted by theoretical analysis. We also demonstrate a controlled and stimuli-responsive twisting motion on a spiral-shaped LBL nanocomposite. By mimicking the motions achieved in nature, this method offers new opportunities for the design and fabrication of functional stimuli-responsive shape-morphing nanoscale and microscale structures for a variety of applications.</description><identifier>ISSN: 0743-7463</identifier><identifier>ISSN: 1520-5827</identifier><identifier>EISSN: 1520-5827</identifier><identifier>DOI: 10.1021/la404955s</identifier><identifier>PMID: 24689908</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><subject>carbon nanotubes ; electrolytes ; energy conservation ; hydrophilicity ; Hydrophobic and Hydrophilic Interactions ; nanocomposites ; Nanocomposites - chemistry ; Nanotechnology ; Nanotubes, Carbon - chemistry ; solar (photovoltaic), solar (thermal), phonons, thermal conductivity, thermoelectric, electrodes - solar, defects, charge transport, materials and chemistry by design, optics, synthesis (novel materials), synthesis (self-assembly) ; solar radiation ; Surface Properties</subject><ispartof>Langmuir, 2014-05, Vol.30 (19), p.5378-5385</ispartof><rights>Copyright © 2014 American Chemical Society</rights><rights>Copyright © 2014 American Chemical Society 2014 American Chemical Society</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a465t-f36c0d8030b035010c2acabc0923dcc404559cc9ddfc68c95ab38a0053edc8ed3</citedby><cites>FETCH-LOGICAL-a465t-f36c0d8030b035010c2acabc0923dcc404559cc9ddfc68c95ab38a0053edc8ed3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/la404955s$$EPDF$$P50$$Gacs$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/la404955s$$EHTML$$P50$$Gacs$$Hfree_for_read</linktohtml><link.rule.ids>230,314,776,780,881,2751,27055,27903,27904,56716,56766</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/24689908$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/1167888$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Andres, Christine M</creatorcontrib><creatorcontrib>Zhu, Jian</creatorcontrib><creatorcontrib>Shyu, Terry</creatorcontrib><creatorcontrib>Flynn, Connor</creatorcontrib><creatorcontrib>Kotov, Nicholas A</creatorcontrib><creatorcontrib>Energy Frontier Research Centers (EFRC)</creatorcontrib><creatorcontrib>Center for Solar and Thermal Energy Conversion (CSTEC)</creatorcontrib><title>Shape-Morphing Nanocomposite Origami</title><title>Langmuir</title><addtitle>Langmuir</addtitle><description>Nature provides a vast array of solid materials that repeatedly and reversibly transform in shape in response to environmental variations. This property is essential, for example, for new energy-saving technologies, efficient collection of solar radiation, and thermal management. Here we report a similar shape-morphing mechanism using differential swelling of hydrophilic polyelectrolyte multilayer inkjets deposited on an LBL carbon nanotube (CNT) composite. The out-of-plane deflection can be precisely controlled, as predicted by theoretical analysis. We also demonstrate a controlled and stimuli-responsive twisting motion on a spiral-shaped LBL nanocomposite. By mimicking the motions achieved in nature, this method offers new opportunities for the design and fabrication of functional stimuli-responsive shape-morphing nanoscale and microscale structures for a variety of applications.</description><subject>carbon nanotubes</subject><subject>electrolytes</subject><subject>energy conservation</subject><subject>hydrophilicity</subject><subject>Hydrophobic and Hydrophilic Interactions</subject><subject>nanocomposites</subject><subject>Nanocomposites - chemistry</subject><subject>Nanotechnology</subject><subject>Nanotubes, Carbon - chemistry</subject><subject>solar (photovoltaic), solar (thermal), phonons, thermal conductivity, thermoelectric, electrodes - solar, defects, charge transport, materials and chemistry by design, optics, synthesis (novel materials), synthesis (self-assembly)</subject><subject>solar radiation</subject><subject>Surface Properties</subject><issn>0743-7463</issn><issn>1520-5827</issn><issn>1520-5827</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><sourceid>N~.</sourceid><sourceid>EIF</sourceid><recordid>eNptkF1LwzAYhYMobk4v_AMyREEvqm-apk1uBBl-gR8X6nXI3mZbRtvUpBX890amQ8GrQPJwcs5DyD6FMwopPa90BpnkPGyQIeUpJFykxSYZQpGxpMhyNiA7ISwBQLJMbpNBmuVCShBDcvS80K1JHpxvF7aZjx9149DVrQu2M-Mnb-e6trtka6arYPa-zxF5vb56mdwm9083d5PL-0RnOe-SGcsRSgEMpsA4UMBUo54iyJSViLEj5xJRluUMc4GS6ykTGoAzU6IwJRuRi1Vu20_reGeazutKtd7W2n8op636-9LYhZq7d_U1P5M0BhyuAlzorAoYN-ACXdMY7BSleSGEiNDJ9y_evfUmdKq2AU1V6ca4Pqg0euJFGmdE9HSFoncheDNbd6GgvtSrtfrIHvwuvyZ_XEfgeAVoDGrpet9El_8EfQJPNIpZ</recordid><startdate>20140520</startdate><enddate>20140520</enddate><creator>Andres, Christine M</creator><creator>Zhu, Jian</creator><creator>Shyu, Terry</creator><creator>Flynn, Connor</creator><creator>Kotov, Nicholas A</creator><general>American Chemical Society</general><scope>N~.</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7S9</scope><scope>L.6</scope><scope>OTOTI</scope><scope>5PM</scope></search><sort><creationdate>20140520</creationdate><title>Shape-Morphing Nanocomposite Origami</title><author>Andres, Christine M ; Zhu, Jian ; Shyu, Terry ; Flynn, Connor ; Kotov, Nicholas A</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a465t-f36c0d8030b035010c2acabc0923dcc404559cc9ddfc68c95ab38a0053edc8ed3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>carbon nanotubes</topic><topic>electrolytes</topic><topic>energy conservation</topic><topic>hydrophilicity</topic><topic>Hydrophobic and Hydrophilic Interactions</topic><topic>nanocomposites</topic><topic>Nanocomposites - chemistry</topic><topic>Nanotechnology</topic><topic>Nanotubes, Carbon - chemistry</topic><topic>solar (photovoltaic), solar (thermal), phonons, thermal conductivity, thermoelectric, electrodes - solar, defects, charge transport, materials and chemistry by design, optics, synthesis (novel materials), synthesis (self-assembly)</topic><topic>solar radiation</topic><topic>Surface Properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Andres, Christine M</creatorcontrib><creatorcontrib>Zhu, Jian</creatorcontrib><creatorcontrib>Shyu, Terry</creatorcontrib><creatorcontrib>Flynn, Connor</creatorcontrib><creatorcontrib>Kotov, Nicholas A</creatorcontrib><creatorcontrib>Energy Frontier Research Centers (EFRC)</creatorcontrib><creatorcontrib>Center for Solar and Thermal Energy Conversion (CSTEC)</creatorcontrib><collection>American Chemical Society (ACS) Open Access</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>AGRICOLA</collection><collection>AGRICOLA - Academic</collection><collection>OSTI.GOV</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Langmuir</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Andres, Christine M</au><au>Zhu, Jian</au><au>Shyu, Terry</au><au>Flynn, Connor</au><au>Kotov, Nicholas A</au><aucorp>Energy Frontier Research Centers (EFRC)</aucorp><aucorp>Center for Solar and Thermal Energy Conversion (CSTEC)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Shape-Morphing Nanocomposite Origami</atitle><jtitle>Langmuir</jtitle><addtitle>Langmuir</addtitle><date>2014-05-20</date><risdate>2014</risdate><volume>30</volume><issue>19</issue><spage>5378</spage><epage>5385</epage><pages>5378-5385</pages><issn>0743-7463</issn><issn>1520-5827</issn><eissn>1520-5827</eissn><abstract>Nature provides a vast array of solid materials that repeatedly and reversibly transform in shape in response to environmental variations. This property is essential, for example, for new energy-saving technologies, efficient collection of solar radiation, and thermal management. Here we report a similar shape-morphing mechanism using differential swelling of hydrophilic polyelectrolyte multilayer inkjets deposited on an LBL carbon nanotube (CNT) composite. The out-of-plane deflection can be precisely controlled, as predicted by theoretical analysis. We also demonstrate a controlled and stimuli-responsive twisting motion on a spiral-shaped LBL nanocomposite. By mimicking the motions achieved in nature, this method offers new opportunities for the design and fabrication of functional stimuli-responsive shape-morphing nanoscale and microscale structures for a variety of applications.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>24689908</pmid><doi>10.1021/la404955s</doi><tpages>8</tpages><oa>free_for_read</oa></addata></record> |
fulltext | fulltext |
identifier | ISSN: 0743-7463 |
ispartof | Langmuir, 2014-05, Vol.30 (19), p.5378-5385 |
issn | 0743-7463 1520-5827 1520-5827 |
language | eng |
recordid | cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_4049491 |
source | MEDLINE; ACS Publications |
subjects | carbon nanotubes electrolytes energy conservation hydrophilicity Hydrophobic and Hydrophilic Interactions nanocomposites Nanocomposites - chemistry Nanotechnology Nanotubes, Carbon - chemistry solar (photovoltaic), solar (thermal), phonons, thermal conductivity, thermoelectric, electrodes - solar, defects, charge transport, materials and chemistry by design, optics, synthesis (novel materials), synthesis (self-assembly) solar radiation Surface Properties |
title | Shape-Morphing Nanocomposite Origami |
url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-25T12%3A03%3A59IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_pubme&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Shape-Morphing%20Nanocomposite%20Origami&rft.jtitle=Langmuir&rft.au=Andres,%20Christine%20M&rft.aucorp=Energy%20Frontier%20Research%20Centers%20(EFRC)&rft.date=2014-05-20&rft.volume=30&rft.issue=19&rft.spage=5378&rft.epage=5385&rft.pages=5378-5385&rft.issn=0743-7463&rft.eissn=1520-5827&rft_id=info:doi/10.1021/la404955s&rft_dat=%3Cproquest_pubme%3E2000572030%3C/proquest_pubme%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2000572030&rft_id=info:pmid/24689908&rfr_iscdi=true |