Carboxylate-Assisted C(sp3)–H Activation in Olefin Metathesis-Relevant Ruthenium Complexes

The mechanism of C–H activation at metathesis-relevant ruthenium­(II) benzylidene complexes was studied both experimentally and computationally. Synthesis of a ruthenium dicarboxylate at a low temperature allowed for direct observation of the C–H activation step, independent of the initial anionic l...

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Veröffentlicht in:	Journal of the American Chemical Society 2014-05, Vol.136 (18), p.6733-6743
Hauptverfasser:	Cannon, Jeffrey S, Zou, Lufeng, Liu, Peng, Lan, Yu, O’Leary, Daniel J, Houk, K. N, Grubbs, Robert H
Format:	Artikel
Sprache:	eng
Schlagworte:	Activation Activation analysis Alkenes - chemistry Carboxylates Carboxylic Acids - chemistry Computation Electronics Ethers geometry isotopes Ligands olefin Ruthenium Ruthenium Compounds - chemistry
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