Palladium-Catalyzed α‑Arylation of Benzylic Phosphonates

A new synthetic route to access diarylmethyl phosphonates is presented. The transformation enables the introduction of aromatic groups on benzylic phosphonates via a deprotonative cross-coupling process (DCCP). The Pd­(OAc)2/CataCXium A-based catalyst afforded a reaction between benzyl diisopropyl p...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Organic letters 2014-03, Vol.16 (5), p.1446-1449
Hauptverfasser:	Montel, Sonia, Raffier, Ludovic, He, Yuying, Walsh, Patrick J
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis catalysts catalytic activity chemical structure cross-coupling reactions Hydrocarbons, Brominated - chemistry Letter Molecular Structure organobromine compounds Organophosphonates - chemical synthesis Organophosphonates - chemistry palladium Palladium - chemistry phosphonates
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!