An Air- and Water-Stable Iodonium Salt Promoter for Facile Thioglycoside Activation

The air- and water-stable iodonium salt phenyl­(trifluoro­ethyl)­iodonium triflimide is shown to activate thioglycosides for glycosylation at room temperature. Both armed and disarmed thioglycosides rapidly undergo glycosylation in 68–97% yield. The reaction conditions are mild and do not require st...

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Veröffentlicht in:	Organic letters 2014-03, Vol.16 (6), p.1780-1782
Hauptverfasser:	Chu, An-Hsiang Adam, Minciunescu, Andrei, Montanari, Vittorio, Kumar, Krishna, Bennett, Clay S
Format:	Artikel
Sprache:	eng
Schlagworte:	Air Gases Glycosylation Letter Mesylates Molecular Structure Stereoisomerism Thioglycosides - chemistry Water
Online-Zugang:	Volltext
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