High Field Dynamic Nuclear Polarization NMR with Surfactant Sheltered Biradicals

We illustrate the ability to place a water-insoluble biradical, bTbk, into a glycerol/water matrix with the assistance of a surfactant, sodium octyl sulfate (SOS). This surfactant approach enables a previously water insoluble biradical, bTbk, with favorable electron–electron dipolar coupling to be u...

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Veröffentlicht in:	The journal of physical chemistry. B 2014-02, Vol.118 (7), p.1825-1830
Hauptverfasser:	Kiesewetter, Matthew K, Michaelis, Vladimir K, Walish, Joseph J, Griffin, Robert G, Swager, Timothy M
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkanesulfonic Acids - chemistry Assembly Cyclic N-Oxides - chemistry Dynamics Electrons Frozen glycerol Glycerol - chemistry Magnetic Resonance Spectroscopy - methods Molecular Structure Nuclear magnetic resonance nuclear magnetic resonance spectroscopy physical chemistry Polarization Propanols - chemistry Sodium Solubility Spiro Compounds - chemistry sulfates Surface-Active Agents - chemistry Surfactants Time Factors urea Urea - chemistry Ureas Water - chemistry
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