Synthesis of Pandamarilactone‑1

The first total synthesis of pan­damari­lactone-1, an alkaloid of Pandanus amaryllifolius, is reported. The nine-step synthesis features furan oxidation with singlet oxygen and then spiro-N,O-acetalization and elimination to generate the natural product and further Pandanus alkaloids, pan­damari­lac...

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Veröffentlicht in:	Organic letters 2014-02, Vol.16 (3), p.884-887
Hauptverfasser:	Seah, Kang Yee, Macnaughton, Sarah J, Dallimore, Jonathan W. P, Robertson, Jeremy
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkaloids - chemical synthesis Alkaloids - chemistry Lactones - chemical synthesis Lactones - chemistry Letter Molecular Structure Pandanaceae - chemistry Pyrrolidines - chemical synthesis Pyrrolidines - chemistry Stereoisomerism
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