High-Pressure Synthesis and Characterization of the Actinide Borate Phosphate U2[BO4][PO4]

High-Pressure Synthesis and Characterization of the Actinide Borate Phosphate U2[BO4][PO4]

A new actinide borate phosphate, U2[BO4][PO4], was synthesized in a Walker‐type multianvil apparatus at 12.5 GPa and 1000 °C. The crystal structure was determined from single‐crystal X‐ray diffraction data collected at room temperature. U2[BO4][PO4] crystallizes in the monoclinic space group P21/c w...

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Veröffentlicht in:European journal of inorganic chemistry 2013-10, Vol.2013 (30), p.5247-5252
Hauptverfasser: Hinteregger, Ernst, Wurst, Klaus, Perfler, Lukas, Kraus, Florian, Huppertz, Hubert
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Actinides
Borate phosphates
High-pressure chemistry
Uranium
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container_issue 30
container_start_page 5247
container_title European journal of inorganic chemistry
container_volume 2013
creator Hinteregger, Ernst
Wurst, Klaus
Perfler, Lukas
Kraus, Florian
Huppertz, Hubert
description A new actinide borate phosphate, U2[BO4][PO4], was synthesized in a Walker‐type multianvil apparatus at 12.5 GPa and 1000 °C. The crystal structure was determined from single‐crystal X‐ray diffraction data collected at room temperature. U2[BO4][PO4] crystallizes in the monoclinic space group P21/c with four formula units per unit cell and the lattice parameters a = 854.6(2), b = 775.3(2), c = 816.3(2) pm, and β = 102.52(3)°. The structure consists of double layers of linked uranium–oxygen polyhedra parallel to [100]. The borate tetrahedra are located between the uranium–oxygen layers inside the double layer. The phosphate groups link the double layers. U2[BO4][PO4] is the first uranium borate phosphate synthesized under high‐pressure/high‐temperature conditions (12.5 GPa and 1000 °C). The new actinide borate phosphate crystallizes in the monoclinic space group P21/c with four formula units per unit cell. The crystal structure consists of isolated [BO4]5– and [PO4]3– groups and double layers formed by uranium and oxygen atoms.
doi_str_mv 10.1002/ejic.201300662
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J. Inorg. Chem</addtitle><date>2013-10-14</date><risdate>2013</risdate><volume>2013</volume><issue>30</issue><spage>5247</spage><epage>5252</epage><pages>5247-5252</pages><issn>1434-1948</issn><eissn>1099-0682</eissn><abstract>A new actinide borate phosphate, U2[BO4][PO4], was synthesized in a Walker‐type multianvil apparatus at 12.5 GPa and 1000 °C. The crystal structure was determined from single‐crystal X‐ray diffraction data collected at room temperature. U2[BO4][PO4] crystallizes in the monoclinic space group P21/c with four formula units per unit cell and the lattice parameters a = 854.6(2), b = 775.3(2), c = 816.3(2) pm, and β = 102.52(3)°. The structure consists of double layers of linked uranium–oxygen polyhedra parallel to [100]. The borate tetrahedra are located between the uranium–oxygen layers inside the double layer. The phosphate groups link the double layers. 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subjects Actinides
Borate phosphates
High-pressure chemistry
Uranium
title High-Pressure Synthesis and Characterization of the Actinide Borate Phosphate U2[BO4][PO4]
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