Effect of concentration gradient on ionic current rectification in polyethyleneimine modified glass nano-pipettes

Ion current rectification dependent on the concentration gradient of KCl solutions was systematically investigated in polyethyleneimine modified glass nano-pipettes with inner diameter of 105 nm. Peak shape dependence of the rectification factor on outer KCl solution concentration was observed when...

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Veröffentlicht in:Scientific reports 2014-02, Vol.4 (1), p.4005, Article 4005
Hauptverfasser: Deng, Xiao Long, Takami, Tomohide, Son, Jong Wan, Kang, Eun Ji, Kawai, Tomoji, Park, Bae Ho
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Takami, Tomohide
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Kang, Eun Ji
Kawai, Tomoji
Park, Bae Ho
description Ion current rectification dependent on the concentration gradient of KCl solutions was systematically investigated in polyethyleneimine modified glass nano-pipettes with inner diameter of 105 nm. Peak shape dependence of the rectification factor on outer KCl solution concentration was observed when inner KCl solution with concentration from 1 mM to 500 mM was used. The peak shape dependence was also observed when the concentrations of the inner and outer KCl solutions were identically controlled. The peak shape in the ion current rectification could be explained by the ion conductance changes through the conical nano-pipette, which result from modulation of ion concentration.
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Peak shape dependence of the rectification factor on outer KCl solution concentration was observed when inner KCl solution with concentration from 1 mM to 500 mM was used. The peak shape dependence was also observed when the concentrations of the inner and outer KCl solutions were identically controlled. 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subjects 119/118
147/135
639/766/119/544
639/766/94
Conductance
Electric Conductivity
Glass - chemistry
Humanities and Social Sciences
Ions
Ions - chemistry
multidisciplinary
Nanopores
Nanostructures
Osmolar Concentration
Polyethyleneimine
Polyethyleneimine - chemistry
Potassium chloride
Potassium Chloride - chemistry
Science
Surface Properties
title Effect of concentration gradient on ionic current rectification in polyethyleneimine modified glass nano-pipettes
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