4-(4-Methyl-phenyl-sulfon-yl)piperazin-1-ium tri-fluoro-acetate

4-(4-Methyl-phenyl-sulfon-yl)piperazin-1-ium tri-fluoro-acetate

In the title salt, C11H17N2O2S(+)·CF3COO(-), the cation is protonated at the secondary piperazine N atom. The dihedral angle between the benzene ring and the piperazine mean plane is 85.54 (10)°. In the crystal, cations and anions are connected by two types of strong N-H⋯O hydrogen bonds into chains...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2013, Vol.69 (Pt 7), p.o1112-o1112
Hauptverfasser: Sreenivasa, S, Mohan, N R, Madhu Chakrapani Rao, T, Suchetan, P A, Palakshamurthy, B S, Vijithkumar
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container_issue Pt 7
container_start_page o1112
container_title Acta crystallographica. Section E, Structure reports online
container_volume 69
creator Sreenivasa, S
Mohan, N R
Madhu Chakrapani Rao, T
Suchetan, P A
Palakshamurthy, B S
Vijithkumar
description In the title salt, C11H17N2O2S(+)·CF3COO(-), the cation is protonated at the secondary piperazine N atom. The dihedral angle between the benzene ring and the piperazine mean plane is 85.54 (10)°. In the crystal, cations and anions are connected by two types of strong N-H⋯O hydrogen bonds into chains extending along [101]. The chains are further assembled into (10-1) layers via stacking inter-actions between benzene rings of the cations [centroid-centroid distance = 3.7319 (13) Å] and a C-H⋯O inter-action involving a piperazine C-H group and a sulfonyl O atom. Another C-H⋯O inter-action between the piperazine ring and the sulfonyl group connects the ions into a three-dimensional network.
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title 4-(4-Methyl-phenyl-sulfon-yl)piperazin-1-ium tri-fluoro-acetate
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