Efficient Iridium-Catalyzed C----H Functionalization/Silylation of Heteroarenes
CSi investigation: The efficient iridium‐catalyzed CH functionalization/silylation of a wide variety of N‐, S‐, and O‐heteroarenes, including N‐unsubstituted indoles, is promoted by 2‐norbornene and features a high level of regioselectivity (see scheme; Ts=p‐toluenesulfonyl, cod=cyclooctadiene)....
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| Veröffentlicht in: | Angewandte Chemie (International ed.) 2008-01, Vol.47 (39), p.7508-7510 |
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| container_issue | 39 |
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| container_title | Angewandte Chemie (International ed.) |
| container_volume | 47 |
| creator | Lu, Biao Falck, John R |
| description | CSi investigation: The efficient iridium‐catalyzed CH functionalization/silylation of a wide variety of N‐, S‐, and O‐heteroarenes, including N‐unsubstituted indoles, is promoted by 2‐norbornene and features a high level of regioselectivity (see scheme; Ts=p‐toluenesulfonyl, cod=cyclooctadiene). |
| doi_str_mv | 10.1002/anie.200802456 |
| format | Article |
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Ts=p‐toluenesulfonyl, cod=cyclooctadiene).</description><subject>Carbon - chemistry</subject><subject>Catalysis</subject><subject>CH activation</subject><subject>heterocycles</subject><subject>Hydrogen - chemistry</subject><subject>Indoles - chemistry</subject><subject>iridium</subject><subject>Iridium - chemistry</subject><subject>Molecular Structure</subject><subject>silanes</subject><subject>Silanes - chemistry</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkUtv1DAUhS0EoqWwZQlZscvUj_iRDVI1mldVtYu2KjvrTnJTDJ64tRNg-uvJkNFQVnjjI_k759o-hLxndMIo5afQOpxwSg3lhVQvyDGTnOVCa_Fy0IUQuTaSHZE3KX0beGOoek2OmFGlUYodk6tZ07jKYdtlq-hq12_yKXTgt09YZ9N8WMts3rdV50IL3j3BTpxeO7_1f2QWmmyJHcYAEVtMb8mrBnzCd_v9hNzOZzfTZX5xtVhNzy7ySiqlcq4Z8hq0LKSkYBoj6BoEY4aiUqhZJQwYqESBQhhJJYMKDTZrXWo0Na3FCfk85j706w3W1fCACN4-RLeBuLUBnP33pHVf7X34YYVWhstiCPi0D4jhscfU2Y1LFXoPLYY-WVXKoqRKDOBkBKsYUorYHIYwancd2F0H9tDBYPjw_Gp_8f2nD0A5Aj-dx-1_4uzZ5Wr2PDwfvS51-OvghfjdKi20tHeXC3uzvONf5ufndjHwH0e-gWDhPrpkb685ZYIyWVDDlPgNfX2swA</recordid><startdate>20080101</startdate><enddate>20080101</enddate><creator>Lu, Biao</creator><creator>Falck, John R</creator><general>Wiley-VCH Verlag</general><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><scope>FBQ</scope><scope>BSCLL</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>5PM</scope></search><sort><creationdate>20080101</creationdate><title>Efficient Iridium-Catalyzed C----H Functionalization/Silylation of Heteroarenes</title><author>Lu, Biao ; 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| identifier | ISSN: 1433-7851 |
| ispartof | Angewandte Chemie (International ed.), 2008-01, Vol.47 (39), p.7508-7510 |
| issn | 1433-7851 1521-3773 |
| language | eng |
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| source | Wiley-Blackwell Journals; MEDLINE |
| subjects | Carbon - chemistry Catalysis CH activation heterocycles Hydrogen - chemistry Indoles - chemistry iridium Iridium - chemistry Molecular Structure silanes Silanes - chemistry |
| title | Efficient Iridium-Catalyzed C----H Functionalization/Silylation of Heteroarenes |
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