Characterization of the FeH Bond in a Three-Coordinate Terminal Hydride Complex of Iron(I)

Three's company: Iron(I) hydride complexes are presented (see picture; N blue, O red) that are the first monomeric open‐shell hydride complexes to be crystallographically verified as being three‐coordinate at the metal. Backbonding into diketiminate π* orbitals stabilizes the low oxidation stat...

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Veröffentlicht in:	Angewandte Chemie International Edition 2012-04, Vol.51 (15), p.3658-3662
Hauptverfasser:	Chiang, Karen P., Scarborough, Christopher C., Horitani, Masaki, Lees, Nicholas S., Ding, Keying, Dugan, Thomas R., Brennessel, William W., Bill, Eckhard, Hoffman, Brian M., Holland, Patrick L.
Format:	Artikel
Sprache:	eng
Schlagworte:	Bonding Crystallography ENDOR Hydrides Hydrogen - chemistry iron Iron - chemistry Iron Compounds - chemistry magnetism Models, Molecular Molecular Structure nitrogenases Orbitals Pictures Spectroscopy, Mossbauer Terminals Valence X-Ray Diffraction
Online-Zugang:	Volltext
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