Electron Paramagnetic Resonance Spectroscopic Study of Copper Hopping in Doped Bis(l‑histidinato)cadmium Dihydrate

Electron paramagnetic resonance (EPR) spectroscopy was used to study Cu(II) dynamic behavior in a doped biological model crystal, bis(l-histidinato)cadmium dihydrate, in order to gain better insight into copper site stability in metalloproteins. Temperature-dependent changes in the low temperature X...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2013-04, Vol.117 (16), p.3414-3427
Hauptverfasser:	Colaneri, Michael J, Vitali, Jacqueline, Kirschbaum, Kristin
Format:	Artikel
Sprache:	eng
Schlagworte:	Analytical, structural and metabolic biochemistry Atomic and molecular physics Binding Sites Biological and medical sciences Cadmium - chemistry Coordination Complexes - chemistry Copper Copper - chemistry Crystallization Dynamics Electron paramagnetic resonance Electron resonance and relaxation Electron Spin Resonance Spectroscopy Exact sciences and technology Fundamental and applied biological sciences. Psychology Histidine - chemistry Hops Kinetics Mathematical analysis Metalloproteins - chemistry Miscellaneous Molecular Mimicry Molecular properties and interactions with photons Physics Proteins Spectra Spectroscopy Temperature Tensors Thermodynamics Water - chemistry
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