Organozinc Chemistry Enabled by Micellar Catalysis. Palladium-Catalyzed Cross-Couplings between Alkyl and Aryl Bromides in Water at Room Temperature

Negishi-like cross-couplings between (functionalized) alkyl and aryl bromides are described. Despite the fact that organozinc reagents are intolerant of water, their formation as well as their use in an aqueous micellar environment is discussed herein. Each component of this complex series of events...

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Veröffentlicht in:Organometallics 2011-11, Vol.30 (22), p.6090-6097
Hauptverfasser: Duplais, Christophe, Krasovskiy, Arkady, Lipshutz, Bruce H
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Sprache:eng
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