An Improbable Monometallic Cluster Entrapped in a Popular Fullerene Cage: YCN@Cs(6)-C82
Since the first proposal that fullerenes are capable of hosting atoms, ions, or clusters by the late Smalley in 1985, tremendous examples of endohedral metallofullerenes (EMFs) have been reported. Breaking the dogma that monometallofullerenes (mono-EMFs) always exist in the form of M@C 2n while clus...
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| Veröffentlicht in: | Scientific reports 2013-03, Vol.3 (1), p.1487, Article 1487 |
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| creator | Yang, Shangfeng Chen, Chuanbao Liu, Fupin Xie, Yunpeng Li, Fengyu Jiao, Mingzhi Suzuki, Mitsuaki Wei, Tao Wang, Song Chen, Zhongfang Lu, Xing Akasaka, Takeshi |
| description | Since the first proposal that fullerenes are capable of hosting atoms, ions, or clusters by the late Smalley in 1985, tremendous examples of endohedral metallofullerenes (EMFs) have been reported. Breaking the dogma that monometallofullerenes (mono-EMFs) always exist in the form of M@C
2n
while clusterfullerenes always require multiple (two to four) metal cations to stabilize a cluster that is unstable as a single moiety, here we show an unprecedented monometallic endohedral clusterfullerene entrapping an yttrium cyanide cluster inside a popular C
82
cage—YCN@C
s
(6)-C
82
. X-ray crystallography and
13
C NMR characterization unambiguously determine the cage symmetry and the endohedal cyanide structure, unexpectedly revealing that the entrapped YCN cluster is triangular. The unprecedented monometallic clusterfullerene structure unveiled by YCN@C
s
(6)-C
82
opens up a new avenue for stabilizing a cluster by a single metal cation within a carbon cage and will surely stimulate further studies on the stability and formation mechanism of EMFs. |
| doi_str_mv | 10.1038/srep01487 |
| format | Article |
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2n
while clusterfullerenes always require multiple (two to four) metal cations to stabilize a cluster that is unstable as a single moiety, here we show an unprecedented monometallic endohedral clusterfullerene entrapping an yttrium cyanide cluster inside a popular C
82
cage—YCN@C
s
(6)-C
82
. X-ray crystallography and
13
C NMR characterization unambiguously determine the cage symmetry and the endohedal cyanide structure, unexpectedly revealing that the entrapped YCN cluster is triangular. The unprecedented monometallic clusterfullerene structure unveiled by YCN@C
s
(6)-C
82
opens up a new avenue for stabilizing a cluster by a single metal cation within a carbon cage and will surely stimulate further studies on the stability and formation mechanism of EMFs.</description><identifier>ISSN: 2045-2322</identifier><identifier>EISSN: 2045-2322</identifier><identifier>DOI: 10.1038/srep01487</identifier><identifier>PMID: 23512079</identifier><language>eng</language><publisher>London: Nature Publishing Group UK</publisher><subject>639/301/119/995 ; 639/301/357/73 ; 639/638/263/911 ; 639/638/403/936 ; Carbon ; Cations ; Crystallography ; Cyanides ; Fullerenes ; Humanities and Social Sciences ; Laboratories ; Materials science ; Metal ions ; multidisciplinary ; Science ; Single crystals ; X-ray crystallography ; Yttrium</subject><ispartof>Scientific reports, 2013-03, Vol.3 (1), p.1487, Article 1487</ispartof><rights>The Author(s) 2013</rights><rights>Copyright Nature Publishing Group Mar 2013</rights><rights>Copyright © 2013, Macmillan Publishers Limited. All rights reserved 2013 Macmillan Publishers Limited. All rights reserved</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3637-1c23a294cce3204056a8a71368111da3149892b13183fdf099cf611a270275f33</citedby><cites>FETCH-LOGICAL-c3637-1c23a294cce3204056a8a71368111da3149892b13183fdf099cf611a270275f33</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC3601605/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC3601605/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,864,885,27923,27924,41119,42188,51575,53790,53792</link.rule.ids></links><search><creatorcontrib>Yang, Shangfeng</creatorcontrib><creatorcontrib>Chen, Chuanbao</creatorcontrib><creatorcontrib>Liu, Fupin</creatorcontrib><creatorcontrib>Xie, Yunpeng</creatorcontrib><creatorcontrib>Li, Fengyu</creatorcontrib><creatorcontrib>Jiao, Mingzhi</creatorcontrib><creatorcontrib>Suzuki, Mitsuaki</creatorcontrib><creatorcontrib>Wei, Tao</creatorcontrib><creatorcontrib>Wang, Song</creatorcontrib><creatorcontrib>Chen, Zhongfang</creatorcontrib><creatorcontrib>Lu, Xing</creatorcontrib><creatorcontrib>Akasaka, Takeshi</creatorcontrib><title>An Improbable Monometallic Cluster Entrapped in a Popular Fullerene Cage: YCN@Cs(6)-C82</title><title>Scientific reports</title><addtitle>Sci Rep</addtitle><description>Since the first proposal that fullerenes are capable of hosting atoms, ions, or clusters by the late Smalley in 1985, tremendous examples of endohedral metallofullerenes (EMFs) have been reported. Breaking the dogma that monometallofullerenes (mono-EMFs) always exist in the form of M@C
2n
while clusterfullerenes always require multiple (two to four) metal cations to stabilize a cluster that is unstable as a single moiety, here we show an unprecedented monometallic endohedral clusterfullerene entrapping an yttrium cyanide cluster inside a popular C
82
cage—YCN@C
s
(6)-C
82
. X-ray crystallography and
13
C NMR characterization unambiguously determine the cage symmetry and the endohedal cyanide structure, unexpectedly revealing that the entrapped YCN cluster is triangular. The unprecedented monometallic clusterfullerene structure unveiled by YCN@C
s
(6)-C
82
opens up a new avenue for stabilizing a cluster by a single metal cation within a carbon cage and will surely stimulate further studies on the stability and formation mechanism of EMFs.</description><subject>639/301/119/995</subject><subject>639/301/357/73</subject><subject>639/638/263/911</subject><subject>639/638/403/936</subject><subject>Carbon</subject><subject>Cations</subject><subject>Crystallography</subject><subject>Cyanides</subject><subject>Fullerenes</subject><subject>Humanities and Social Sciences</subject><subject>Laboratories</subject><subject>Materials science</subject><subject>Metal ions</subject><subject>multidisciplinary</subject><subject>Science</subject><subject>Single crystals</subject><subject>X-ray crystallography</subject><subject>Yttrium</subject><issn>2045-2322</issn><issn>2045-2322</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><sourceid>C6C</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNplkV1LwzAUhoMobsxd-A8C3jihmpP00wtxlE2F-XGhiFchbdPZkTY1aQX_vRkbY-K5yYE8vHnIi9ApkEsgLL6yRrYE_Dg6QENK_MCjjNLDvX2AxtauiJuAJj4kx2hAWQCURMkQvU8b_FC3RmciUxI_6kbXshNKVTlOVW87afCs6YxoW1ngqsECv-i2V8Lgea-UNLKROBVLeY0_0qfb1J6HEy-N6Qk6KoWycrw9R-htPntN773F891DOl14OQtZ5EFOmXBWeS6ZEyZBKGIRAQtjACgEAz-JE5oBg5iVRUmSJC9DAEEjQqOgZGyEbja5bZ_Vssjl2lXx1lS1MD9ci4r_vWmqT77U35yFBEISuICzbYDRX720HV_p3jTOmUOcRL5TCImjJhsqN9q6Hy93LwDh6xr4rgbHXmxY65hmKc1e4j_4F3CuhHE</recordid><startdate>20130319</startdate><enddate>20130319</enddate><creator>Yang, Shangfeng</creator><creator>Chen, Chuanbao</creator><creator>Liu, Fupin</creator><creator>Xie, Yunpeng</creator><creator>Li, Fengyu</creator><creator>Jiao, Mingzhi</creator><creator>Suzuki, Mitsuaki</creator><creator>Wei, Tao</creator><creator>Wang, Song</creator><creator>Chen, Zhongfang</creator><creator>Lu, Xing</creator><creator>Akasaka, Takeshi</creator><general>Nature Publishing Group UK</general><general>Nature Publishing Group</general><scope>C6C</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7X7</scope><scope>7XB</scope><scope>88A</scope><scope>88E</scope><scope>88I</scope><scope>8FE</scope><scope>8FH</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>ABUWG</scope><scope>AEUYN</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BBNVY</scope><scope>BENPR</scope><scope>BHPHI</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>FYUFA</scope><scope>GHDGH</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>K9.</scope><scope>LK8</scope><scope>M0S</scope><scope>M1P</scope><scope>M2P</scope><scope>M7P</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope><scope>5PM</scope></search><sort><creationdate>20130319</creationdate><title>An Improbable Monometallic Cluster Entrapped in a Popular Fullerene Cage: YCN@Cs(6)-C82</title><author>Yang, Shangfeng ; Chen, Chuanbao ; Liu, Fupin ; Xie, Yunpeng ; Li, Fengyu ; Jiao, Mingzhi ; Suzuki, Mitsuaki ; Wei, Tao ; Wang, Song ; Chen, Zhongfang ; Lu, Xing ; Akasaka, Takeshi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3637-1c23a294cce3204056a8a71368111da3149892b13183fdf099cf611a270275f33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>639/301/119/995</topic><topic>639/301/357/73</topic><topic>639/638/263/911</topic><topic>639/638/403/936</topic><topic>Carbon</topic><topic>Cations</topic><topic>Crystallography</topic><topic>Cyanides</topic><topic>Fullerenes</topic><topic>Humanities and Social Sciences</topic><topic>Laboratories</topic><topic>Materials science</topic><topic>Metal ions</topic><topic>multidisciplinary</topic><topic>Science</topic><topic>Single crystals</topic><topic>X-ray crystallography</topic><topic>Yttrium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yang, Shangfeng</creatorcontrib><creatorcontrib>Chen, Chuanbao</creatorcontrib><creatorcontrib>Liu, Fupin</creatorcontrib><creatorcontrib>Xie, Yunpeng</creatorcontrib><creatorcontrib>Li, Fengyu</creatorcontrib><creatorcontrib>Jiao, Mingzhi</creatorcontrib><creatorcontrib>Suzuki, Mitsuaki</creatorcontrib><creatorcontrib>Wei, Tao</creatorcontrib><creatorcontrib>Wang, Song</creatorcontrib><creatorcontrib>Chen, Zhongfang</creatorcontrib><creatorcontrib>Lu, Xing</creatorcontrib><creatorcontrib>Akasaka, Takeshi</creatorcontrib><collection>Springer Open Access</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>ProQuest Health and Medical</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Biology Database (Alumni Edition)</collection><collection>Medical Database (Alumni Edition)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Natural Science Collection</collection><collection>Hospital Premium Collection</collection><collection>Hospital Premium Collection (Alumni Edition)</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest One Sustainability</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>Biological Science Collection</collection><collection>ProQuest Central</collection><collection>Natural Science Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>Health Research Premium Collection</collection><collection>Health Research Premium Collection (Alumni)</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>ProQuest Biological Science Collection</collection><collection>Health & Medical Collection (Alumni Edition)</collection><collection>Medical Database</collection><collection>ProQuest Science Journals</collection><collection>ProQuest Biological Science Journals</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central Basic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Scientific reports</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yang, Shangfeng</au><au>Chen, Chuanbao</au><au>Liu, Fupin</au><au>Xie, Yunpeng</au><au>Li, Fengyu</au><au>Jiao, Mingzhi</au><au>Suzuki, Mitsuaki</au><au>Wei, Tao</au><au>Wang, Song</au><au>Chen, Zhongfang</au><au>Lu, Xing</au><au>Akasaka, Takeshi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>An Improbable Monometallic Cluster Entrapped in a Popular Fullerene Cage: YCN@Cs(6)-C82</atitle><jtitle>Scientific reports</jtitle><stitle>Sci Rep</stitle><date>2013-03-19</date><risdate>2013</risdate><volume>3</volume><issue>1</issue><spage>1487</spage><pages>1487-</pages><artnum>1487</artnum><issn>2045-2322</issn><eissn>2045-2322</eissn><abstract>Since the first proposal that fullerenes are capable of hosting atoms, ions, or clusters by the late Smalley in 1985, tremendous examples of endohedral metallofullerenes (EMFs) have been reported. Breaking the dogma that monometallofullerenes (mono-EMFs) always exist in the form of M@C
2n
while clusterfullerenes always require multiple (two to four) metal cations to stabilize a cluster that is unstable as a single moiety, here we show an unprecedented monometallic endohedral clusterfullerene entrapping an yttrium cyanide cluster inside a popular C
82
cage—YCN@C
s
(6)-C
82
. X-ray crystallography and
13
C NMR characterization unambiguously determine the cage symmetry and the endohedal cyanide structure, unexpectedly revealing that the entrapped YCN cluster is triangular. The unprecedented monometallic clusterfullerene structure unveiled by YCN@C
s
(6)-C
82
opens up a new avenue for stabilizing a cluster by a single metal cation within a carbon cage and will surely stimulate further studies on the stability and formation mechanism of EMFs.</abstract><cop>London</cop><pub>Nature Publishing Group UK</pub><pmid>23512079</pmid><doi>10.1038/srep01487</doi><oa>free_for_read</oa></addata></record> |
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| source | Springer Open Access; DOAJ Directory of Open Access Journals; Nature Journals Online; EZB-FREE-00999 freely available EZB journals; PubMed Central; Free Full-Text Journals in Chemistry |
| subjects | 639/301/119/995 639/301/357/73 639/638/263/911 639/638/403/936 Carbon Cations Crystallography Cyanides Fullerenes Humanities and Social Sciences Laboratories Materials science Metal ions multidisciplinary Science Single crystals X-ray crystallography Yttrium |
| title | An Improbable Monometallic Cluster Entrapped in a Popular Fullerene Cage: YCN@Cs(6)-C82 |
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