Identification of Lactam–Lactim Tautomers of Aromatic Heterocycles in Aqueous Solution Using 2D IR Spectroscopy

The tautomerism of aromatic heterocycles is of great interest because it directly affects their chemical properties and biological function. The tautomerism of 2-pyridone, 6-chloro-2-pyridone, and 4-pyrimidinone has been examined in D2O using FTIR, two-dimensional IR (2D IR) spectroscopy, and densit...

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Veröffentlicht in:	The journal of physical chemistry letters 2012-11, Vol.3 (22), p.3302-3306
Hauptverfasser:	Peng, Chunte Sam, Tokmakoff, Andrei
Format:	Artikel
Sprache:	eng
Schlagworte:	Spectroscopy, Photochemistry, and Excited States
Online-Zugang:	Volltext
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