Asymmetric Approach toward Chiral Cyclohex-2-enones from Anisoles via an Enantioselective Isomerization by a New Chiral Diamine Catalyst

A 3-step asymmetric approach toward the optically active chiral cyclohex-2-enones from anisoles has been developed. The crucial asymmetric induction step is an unprecedented catalytic enantioselective isomerization of β,γ-unsaturated cyclohex-3-en-1-ones to the corresponding α,β-unsaturated chiral e...

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Veröffentlicht in:	Journal of the American Chemical Society 2012-11, Vol.134 (44), p.18209-18212
Hauptverfasser:	Lee, Jung Hwa, Deng, Li
Format:	Artikel
Sprache:	eng
Schlagworte:	Anisoles - chemistry Catalysis Cyclohexanones - chemical synthesis Cyclohexanones - chemistry Diamines - chemistry Isomerism Sesquiterpenes - chemical synthesis
Online-Zugang:	Volltext
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