CO2 Adsorption on Activated Carbon Honeycomb-Monoliths: A Comparison of Langmuir and Tóth Models

CO2 Adsorption on Activated Carbon Honeycomb-Monoliths: A Comparison of Langmuir and Tóth Models

Activated carbon honeycomb-monoliths with different textural properties were prepared by chemical activation of African palm shells with H3PO4, ZnCl2 and CaCl2 aqueous solutions of various concentrations. The adsorbents obtained were characterized by N2 adsorption at 77 K, and their carbon dioxide a...

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Veröffentlicht in:International journal of molecular sciences 2012-07, Vol.13 (7), p.8388-8397
Hauptverfasser: Vargas, Diana P., Giraldo, Liliana, Moreno-Piraján, Juan C.
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Sprache:eng
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Activated carbon
Adsorbents
Adsorption
Aqueous solutions
Carbon dioxide
Energy
Equilibrium
Porous materials
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Giraldo, Liliana
Moreno-Piraján, Juan C.
description Activated carbon honeycomb-monoliths with different textural properties were prepared by chemical activation of African palm shells with H3PO4, ZnCl2 and CaCl2 aqueous solutions of various concentrations. The adsorbents obtained were characterized by N2 adsorption at 77 K, and their carbon dioxide adsorption capacities were measured at 273 K and 1 Bar in volumetric adsorption equipment. The experimental adsorption isotherms were fitted to Langmuir and Tóth models, and a better fit was observed to Tóth equation with a correlation coefficient of 0.999. The maximum experimental values for adsorption capacity at the highest pressure (2.627–5.756 mmol·g−1) are between the calculated data in the two models.
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source MDPI - Multidisciplinary Digital Publishing Institute; EZB-FREE-00999 freely available EZB journals; PubMed Central
subjects Activated carbon
Adsorbents
Adsorption
Aqueous solutions
Carbon dioxide
Energy
Equilibrium
Porous materials
title CO2 Adsorption on Activated Carbon Honeycomb-Monoliths: A Comparison of Langmuir and Tóth Models
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