meso-Arylporpholactones and their Reduction Products

The rational syntheses of meso-tetraaryl-3-oxo-2-oxaporphyrins 5, known as porpholactones, via MnO4 –-mediated oxidations of the corresponding meso-tetraaryl-2,3-dihydroxychlorins (7) is detailed. Since chlorin 7 is prepared from the parent porphyrin 1, this amounts to a 2-step replacement of a pyrr...

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Veröffentlicht in:	Journal of organic chemistry 2012-08, Vol.77 (15), p.6480-6494
Hauptverfasser:	Brückner, Christian, Ogikubo, Junichi, McCarthy, Jason R, Akhigbe, Joshua, Hyland, Michael A, Daddario, Pedro, Worlinsky, Jill L, Zeller, Matthias, Engle, James T, Ziegler, Christopher J, Ranaghan, Matthew J, Sandberg, Megan N, Birge, Robert R
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical reactivity Chemistry chlorins Crystallography, X-Ray Exact sciences and technology Heterocyclic compounds Heterocyclic compounds with n hetero atom and also o and/or s, se, te hetero atoms Heterocyclic compounds with only one n hetero atom and condensed derivatives Heterocyclic compounds with several n hetero atoms in the same ring, in separated rings or in fused rings Lactones - chemical synthesis Lactones - chemistry Lewis bases Models, Molecular moieties Molecular Structure optical properties Organic chemistry oxazoles oxidation Oxidation-Reduction oxygen Preparations and properties Reactivity and mechanisms
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