Transition-Metal-Catalyzed Denitrogenative Transannulation: Converting Triazoles into Other Heterocyclic Systems
Transition metal catalyzed denitrogenative transannulation of a triazole ring has recently received considerable attention as a new concept for the construction of diverse nitrogen‐containing heterocyclic cores. This method allows a single‐step synthesis of complex nitrogen heterocycles from easily...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2012-01, Vol.51 (4), p.862-872 |
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| creator | Chattopadhyay, Buddhadeb Gevorgyan, Vladimir |
| description | Transition metal catalyzed denitrogenative transannulation of a triazole ring has recently received considerable attention as a new concept for the construction of diverse nitrogen‐containing heterocyclic cores. This method allows a single‐step synthesis of complex nitrogen heterocycles from easily available and cheap triazole precursors. In this Minireview, recent progress of the transition metal catalyzed denitrogenative transannulation of a triazole ring, which was discovered in 2007, is discussed.
One two three: Transition‐metal catalyzed denitrogenative transannulation of 1,2,3‐triazole rings has recently received increasing attention as a new concept for the construction of diverse nitrogen‐containing heterocyclic cores in a single step (see scheme). |
| doi_str_mv | 10.1002/anie.201104807 |
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| ispartof | Angewandte Chemie International Edition, 2012-01, Vol.51 (4), p.862-872 |
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| source | MEDLINE; Wiley Online Library Journals Frontfile Complete |
| subjects | Alkenes - chemistry Alkynes - chemistry Catalysis Cyanides - chemistry Cyclization Heterocyclic Compounds - chemical synthesis Heterocyclic Compounds - chemistry Nitriles - chemistry nitrogen heterocycles synthetic methods transannulation Transition Elements - chemistry transition metals Triazoles - chemistry |
| title | Transition-Metal-Catalyzed Denitrogenative Transannulation: Converting Triazoles into Other Heterocyclic Systems |
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