Aerosol Synthesis of Cargo-Filled Graphene Nanosacks
Water microdroplets containing graphene oxide and a second solute are shown to spontaneously segregate into sack-cargo nanostructures upon drying. Analytical modeling and molecular dynamics suggest the sacks form when slow-diffusing graphene oxide preferentially accumulates and adsorbs at the recedi...
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| Veröffentlicht in: | Nano letters 2012-04, Vol.12 (4), p.1996-2002 |
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| container_end_page | 2002 |
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| container_issue | 4 |
| container_start_page | 1996 |
| container_title | Nano letters |
| container_volume | 12 |
| creator | Chen, Yantao Guo, Fei Jachak, Ashish Kim, Sang-Pil Datta, Dibakar Liu, Jingyu Kulaots, Indrek Vaslet, Charles Jang, Hee Dong Huang, Jiaxing Kane, Agnes Shenoy, Vivek B Hurt, Robert H |
| description | Water microdroplets containing graphene oxide and a second solute are shown to spontaneously segregate into sack-cargo nanostructures upon drying. Analytical modeling and molecular dynamics suggest the sacks form when slow-diffusing graphene oxide preferentially accumulates and adsorbs at the receding air–water interface, followed by capillary collapse. Cargo-filled graphene nanosacks can be nanomanufactured by a simple, continuous, scalable process and are promising for many applications where nanoscale materials should be isolated from the environment or biological tissue. |
| doi_str_mv | 10.1021/nl2045952 |
| format | Article |
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Analytical modeling and molecular dynamics suggest the sacks form when slow-diffusing graphene oxide preferentially accumulates and adsorbs at the receding air–water interface, followed by capillary collapse. Cargo-filled graphene nanosacks can be nanomanufactured by a simple, continuous, scalable process and are promising for many applications where nanoscale materials should be isolated from the environment or biological tissue.</description><identifier>ISSN: 1530-6984</identifier><identifier>EISSN: 1530-6992</identifier><identifier>DOI: 10.1021/nl2045952</identifier><identifier>PMID: 22429091</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Aerosols ; Aerosols - chemical synthesis ; Aerosols - chemistry ; Cell Survival - drug effects ; Collapse ; Condensed matter: structure, mechanical and thermal properties ; Cross-disciplinary physics: materials science; rheology ; Drying ; Epithelial Cells - cytology ; Epithelial Cells - drug effects ; Exact sciences and technology ; Fullerenes and related materials; diamonds, graphite ; Graphene ; Graphite - chemistry ; Humans ; Low-dimensional structures (superlattices, quantum well structures, multilayers): structure, and nonelectronic properties ; Materials science ; Mathematical analysis ; Molecular dynamics ; Molecular Dynamics Simulation ; Nanostructure ; Nanostructures - chemistry ; Nickel - chemistry ; Nickel - pharmacology ; Oxides ; Oxides - chemistry ; Oxides - pharmacology ; Particle Size ; Physics ; Specific materials ; Structure-Activity Relationship ; Surface Properties ; Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties) ; Synthesis ; Water - chemistry</subject><ispartof>Nano letters, 2012-04, Vol.12 (4), p.1996-2002</ispartof><rights>Copyright © 2012 American Chemical Society</rights><rights>2015 INIST-CNRS</rights><rights>2012 American Chemical Society</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a533t-19b1714ad10f8b8f7c92aa79979a2b9f4142ca6cf273b4cdc47cab3498e11bf3</citedby><cites>FETCH-LOGICAL-a533t-19b1714ad10f8b8f7c92aa79979a2b9f4142ca6cf273b4cdc47cab3498e11bf3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/nl2045952$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/nl2045952$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>230,314,780,784,885,2765,27076,27924,27925,56738,56788</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=25796533$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/22429091$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Chen, Yantao</creatorcontrib><creatorcontrib>Guo, Fei</creatorcontrib><creatorcontrib>Jachak, Ashish</creatorcontrib><creatorcontrib>Kim, Sang-Pil</creatorcontrib><creatorcontrib>Datta, Dibakar</creatorcontrib><creatorcontrib>Liu, Jingyu</creatorcontrib><creatorcontrib>Kulaots, Indrek</creatorcontrib><creatorcontrib>Vaslet, Charles</creatorcontrib><creatorcontrib>Jang, Hee Dong</creatorcontrib><creatorcontrib>Huang, Jiaxing</creatorcontrib><creatorcontrib>Kane, Agnes</creatorcontrib><creatorcontrib>Shenoy, Vivek B</creatorcontrib><creatorcontrib>Hurt, Robert H</creatorcontrib><title>Aerosol Synthesis of Cargo-Filled Graphene Nanosacks</title><title>Nano letters</title><addtitle>Nano Lett</addtitle><description>Water microdroplets containing graphene oxide and a second solute are shown to spontaneously segregate into sack-cargo nanostructures upon drying. Analytical modeling and molecular dynamics suggest the sacks form when slow-diffusing graphene oxide preferentially accumulates and adsorbs at the receding air–water interface, followed by capillary collapse. Cargo-filled graphene nanosacks can be nanomanufactured by a simple, continuous, scalable process and are promising for many applications where nanoscale materials should be isolated from the environment or biological tissue.</description><subject>Aerosols</subject><subject>Aerosols - chemical synthesis</subject><subject>Aerosols - chemistry</subject><subject>Cell Survival - drug effects</subject><subject>Collapse</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>Drying</subject><subject>Epithelial Cells - cytology</subject><subject>Epithelial Cells - drug effects</subject><subject>Exact sciences and technology</subject><subject>Fullerenes and related materials; diamonds, graphite</subject><subject>Graphene</subject><subject>Graphite - chemistry</subject><subject>Humans</subject><subject>Low-dimensional structures (superlattices, quantum well structures, multilayers): structure, and nonelectronic properties</subject><subject>Materials science</subject><subject>Mathematical analysis</subject><subject>Molecular dynamics</subject><subject>Molecular Dynamics Simulation</subject><subject>Nanostructure</subject><subject>Nanostructures - chemistry</subject><subject>Nickel - chemistry</subject><subject>Nickel - pharmacology</subject><subject>Oxides</subject><subject>Oxides - chemistry</subject><subject>Oxides - pharmacology</subject><subject>Particle Size</subject><subject>Physics</subject><subject>Specific materials</subject><subject>Structure-Activity Relationship</subject><subject>Surface Properties</subject><subject>Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties)</subject><subject>Synthesis</subject><subject>Water - chemistry</subject><issn>1530-6984</issn><issn>1530-6992</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNptkE1LAzEQhoMotlYP_gHZi6CH1XztprkIpdgqFD3Ye5hNk3ZrmtSkFfrvXWltFTzNwDy87_AgdEnwHcGU3HtHMS9kQY9QmxQM56WU9Hi_d3kLnaU0xxhLVuBT1KKUU4klaSPeMzGk4LK3jV_NTKpTFmzWhzgN-aB2zkyyYYTlzHiTvYAPCfR7OkcnFlwyF7vZQePB47j_lI9eh8_93iiHgrFVTmRFBOEwIdh2q64VWlIAIaWQQCtpOeFUQ6ktFazieqK50FAxLruGkMqyDnrYxi7X1cJMtPGrCE4tY72AuFEBavX34uuZmoZPxVghCMNNwM0uIIaPtUkrtaiTNs6BN2GdFBFlI06WmDTo7RbVjY4Ujd3XEKy-Jau95Ia9-v3Xnvyx2gDXOwCSBmcjeF2nA1cIWTaGDhzopOZhHX1j85_CL1dJj74</recordid><startdate>20120411</startdate><enddate>20120411</enddate><creator>Chen, Yantao</creator><creator>Guo, Fei</creator><creator>Jachak, Ashish</creator><creator>Kim, Sang-Pil</creator><creator>Datta, Dibakar</creator><creator>Liu, Jingyu</creator><creator>Kulaots, Indrek</creator><creator>Vaslet, Charles</creator><creator>Jang, Hee Dong</creator><creator>Huang, Jiaxing</creator><creator>Kane, Agnes</creator><creator>Shenoy, Vivek B</creator><creator>Hurt, Robert H</creator><general>American Chemical Society</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>5PM</scope></search><sort><creationdate>20120411</creationdate><title>Aerosol Synthesis of Cargo-Filled Graphene Nanosacks</title><author>Chen, Yantao ; Guo, Fei ; Jachak, Ashish ; Kim, Sang-Pil ; Datta, Dibakar ; Liu, Jingyu ; Kulaots, Indrek ; Vaslet, Charles ; Jang, Hee Dong ; Huang, Jiaxing ; Kane, Agnes ; Shenoy, Vivek B ; Hurt, Robert H</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a533t-19b1714ad10f8b8f7c92aa79979a2b9f4142ca6cf273b4cdc47cab3498e11bf3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Aerosols</topic><topic>Aerosols - chemical synthesis</topic><topic>Aerosols - chemistry</topic><topic>Cell Survival - drug effects</topic><topic>Collapse</topic><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Cross-disciplinary physics: materials science; rheology</topic><topic>Drying</topic><topic>Epithelial Cells - cytology</topic><topic>Epithelial Cells - drug effects</topic><topic>Exact sciences and technology</topic><topic>Fullerenes and related materials; diamonds, graphite</topic><topic>Graphene</topic><topic>Graphite - chemistry</topic><topic>Humans</topic><topic>Low-dimensional structures (superlattices, quantum well structures, multilayers): structure, and nonelectronic properties</topic><topic>Materials science</topic><topic>Mathematical analysis</topic><topic>Molecular dynamics</topic><topic>Molecular Dynamics Simulation</topic><topic>Nanostructure</topic><topic>Nanostructures - chemistry</topic><topic>Nickel - chemistry</topic><topic>Nickel - pharmacology</topic><topic>Oxides</topic><topic>Oxides - chemistry</topic><topic>Oxides - pharmacology</topic><topic>Particle Size</topic><topic>Physics</topic><topic>Specific materials</topic><topic>Structure-Activity Relationship</topic><topic>Surface Properties</topic><topic>Surfaces and interfaces; 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Analytical modeling and molecular dynamics suggest the sacks form when slow-diffusing graphene oxide preferentially accumulates and adsorbs at the receding air–water interface, followed by capillary collapse. Cargo-filled graphene nanosacks can be nanomanufactured by a simple, continuous, scalable process and are promising for many applications where nanoscale materials should be isolated from the environment or biological tissue.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>22429091</pmid><doi>10.1021/nl2045952</doi><tpages>7</tpages><oa>free_for_read</oa></addata></record> |
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| ispartof | Nano letters, 2012-04, Vol.12 (4), p.1996-2002 |
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| source | MEDLINE; American Chemical Society Journals |
| subjects | Aerosols Aerosols - chemical synthesis Aerosols - chemistry Cell Survival - drug effects Collapse Condensed matter: structure, mechanical and thermal properties Cross-disciplinary physics: materials science rheology Drying Epithelial Cells - cytology Epithelial Cells - drug effects Exact sciences and technology Fullerenes and related materials diamonds, graphite Graphene Graphite - chemistry Humans Low-dimensional structures (superlattices, quantum well structures, multilayers): structure, and nonelectronic properties Materials science Mathematical analysis Molecular dynamics Molecular Dynamics Simulation Nanostructure Nanostructures - chemistry Nickel - chemistry Nickel - pharmacology Oxides Oxides - chemistry Oxides - pharmacology Particle Size Physics Specific materials Structure-Activity Relationship Surface Properties Surfaces and interfaces thin films and whiskers (structure and nonelectronic properties) Synthesis Water - chemistry |
| title | Aerosol Synthesis of Cargo-Filled Graphene Nanosacks |
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