Silyl Glyoxylates. Conception and Realization of Flexible Conjunctive Reagents for Multicomponent Coupling

This Perspective describes the discovery and development of silyl glyoxylates, a new family of conjunctive reagents for use in multicomponent coupling reactions. The selection of the nucleophilic and electrophilic components determines whether the silyl glyoxylate reagent will function as a syntheti...

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Veröffentlicht in:	Journal of organic chemistry 2012-05, Vol.77 (10), p.4503-4515
Hauptverfasser:	Boyce, Gregory R, Greszler, Stephen N, Johnson, Jeffrey S, Linghu, Xin, Malinowski, Justin T, Nicewicz, David A, Satterfield, Andrew D, Schmitt, Daniel C, Steward, Kimberly M
Format:	Artikel
Sprache:	eng
Schlagworte:	Aliphatic compounds Catalysis catalytic activity chemical reactions Chemistry Exact sciences and technology glycolic acid Glyoxylates - chemistry Indicators and Reagents - chemistry Lewis acids Lewis bases moieties Molecular Structure new family Organic chemistry Organometalloidal and organometallic compounds Organosilicon Compounds - chemistry Preparations and properties Si derivatives Stereoisomerism
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