First enantioseparation and circular dichroism spectra of Au38 clusters protected by achiral ligands

Bestowing chirality to metals is central in fields such as heterogeneous catalysis and modern optics. Although the bulk phase of metals is symmetric, their surfaces can become chiral through adsorption of molecules. Interestingly, even achiral molecules can lead to locally chiral, though globally ra...

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Veröffentlicht in:Nature communications 2012-04, Vol.3 (1), p.798-798, Article 798
Hauptverfasser: Dolamic, Igor, Knoppe, Stefan, Dass, Amala, Bürgi, Thomas
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Sprache:eng
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