Plasmonic-Based Imaging of Local Square Wave Voltammetry

Square wave voltammetry (SWV) is widely used in electrochemical analysis and sensors because of its high sensitivity and efficient rejection of background current, but SWV by the conventional electrochemical detection method does not provide spatial resolution. We report here a plasmonic method to i...

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Veröffentlicht in:Analytical chemistry (Washington) 2011-10, Vol.83 (19), p.7394-7399
Hauptverfasser: Shan, Xiaonan, Wang, Shaopeng, Wang, Wei, Tao, Nongjian
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creator Shan, Xiaonan
Wang, Shaopeng
Wang, Wei
Tao, Nongjian
description Square wave voltammetry (SWV) is widely used in electrochemical analysis and sensors because of its high sensitivity and efficient rejection of background current, but SWV by the conventional electrochemical detection method does not provide spatial resolution. We report here a plasmonic method to image local SWV, which opens the door for analyzing heterogeneous electrochemical reactions and for high-throughput detections of microarrays. We describe the basic principle, validate the principle by comparing the plasmonic-based SWV with those obtained with the conventional method, and demonstrate imaging capability for local electrochemical analysis.
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subjects Analytical chemistry
Chemical reactions
Chemistry
Comparative analysis
Electrochemical methods
Electrochemical Techniques
Electrochemistry
Electrodes
Exact sciences and technology
General, instrumentation
Sensors
title Plasmonic-Based Imaging of Local Square Wave Voltammetry
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