Intramolecular monomer-on-monomer (MoM) Mitsunobu cyclization for the synthesis of benzofused thiadiazepine-dioxides
The utilization of a monomer-on-monomer (MoM) intramolecular Mitsunobu cyclization reaction employing norbornenyl-tagged (Nb-tagged) reagents is reported for the synthesis of benzofused thiadiazepine-dioxides. Facile purification was achieved via ring-opening metathesis (ROM) polymerization initiate...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2011-12, Vol.47 (46), p.12524-12526 |
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| container_title | Chemical communications (Cambridge, England) |
| container_volume | 47 |
| creator | Maity, Pradip K Kainz, Quirin M Faisal, Saqib Rolfe, Alan Samarakoon, Thiwanka B Basha, Fatima Z Reiser, Oliver Hanson, Paul R |
| description | The utilization of a monomer-on-monomer (MoM) intramolecular Mitsunobu cyclization reaction employing norbornenyl-tagged (Nb-tagged) reagents is reported for the synthesis of benzofused thiadiazepine-dioxides. Facile purification was achieved via ring-opening metathesis (ROM) polymerization initiated by one of three metathesis catalyst methods: (i) free metathesis catalyst, (ii) surface-initiated catalyst-armed silica, or (iii) surface-initiated catalyst-armed Co/C magnetic nanoparticles. |
| doi_str_mv | 10.1039/c1cc14807a |
| format | Article |
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| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2011-12, Vol.47 (46), p.12524-12526 |
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| source | MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Benzene - chemistry Catalysts Chemistry Techniques, Synthetic - methods cobalt Cyclization cyclization reactions Decomposition reactions magnetism Metathesis Nanoparticles Nanoparticles - chemistry Niobium polymerization Purification silica Synthesis Thiadiazines - chemical synthesis Thiadiazines - chemistry Utilization |
| title | Intramolecular monomer-on-monomer (MoM) Mitsunobu cyclization for the synthesis of benzofused thiadiazepine-dioxides |
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