An Approach to Mimicking the Sesquiterpene Cyclase Phase by Nickel-Promoted Diene/Alkyne Cooligomerization

Artificially mimicking the cyclase phase of terpene biosynthesis inspires the invention of new methodologies, since working with carbogenic frameworks containing minimal functionality limits the chemist’s toolbox of synthetic strategies. For example, the construction of terpene skeletons from five-c...

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Veröffentlicht in:	Journal of organic chemistry 2012-01, Vol.77 (2), p.825-842
Hauptverfasser:	Holte, Dane, Götz, Daniel C. G, Baran, Phil S
Format:	Artikel
Sprache:	eng
Schlagworte:	Alicyclic compounds, terpenoids, prostaglandins, steroids Alkynes - chemical synthesis Alkynes - chemistry Aroma and flavouring agent industries Bioconversions. Hemisynthesis Biological and medical sciences Biotechnology Butadienes - chemistry Carbon-Carbon Lyases Catalysis Chemistry Chemistry Techniques, Synthetic - methods Exact sciences and technology Food industries Fundamental and applied biological sciences. Psychology Hemiterpenes - chemistry Methods. Procedures. Technologies Molecular Mimicry Molecular Structure Nickel - chemistry Organic chemistry Pentanes - chemistry Preparations and properties Terpenoids
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