Asymmetric Synthesis of Diamine Derivatives via Sequential Palladium and Rhodium Catalysis

The use of a bifunctional nitrogen nucleophile and an allyl carbonate starting material in successive enantioselective palladium- and diastereoselective rhodium-catalyzed reactions enables the rapid assembly of unique amino aziridine products. Further elaboration of these materials affords complex,...

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Veröffentlicht in:	Journal of the American Chemical Society 2009-04, Vol.131 (12), p.4190-4191
Hauptverfasser:	Trost, Barry M, Malhotra, Sushant, Olson, David E, Maruniak, Autumn, Du Bois, J
Format:	Artikel
Sprache:	eng
Schlagworte:	Allyl Compounds - chemistry Catalysis Chemistry, Organic - methods Diamines - chemistry Ligands Models, Chemical Molecular Structure Nitrogen - chemistry Oxygen - chemistry Palladium - chemistry Polyamines - chemistry Rhodium - chemistry Solvents - chemistry
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