Diaqua-bis-(1H-imidazole-4-carboxyl-ato-κN,O)zinc

Diaqua-bis-(1H-imidazole-4-carboxyl-ato-κN,O)zinc

In the title compound, [Zn(C(4)H(3)N(2)O(2))(2)(H(2)O)(2)], the Zn(II) ion is situated on a twofold rotation axis and exhibits a distorted octa-hedral coordination configuration. The equatorial plane contains two cis-oriented bidentate 1H-imidazole-4-carboxyl-ate ligands and the axial positions are...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2011-07, Vol.67 (Pt 7), p.m897-m897
Hauptverfasser: Shuai, Wenlin, Cai, Songliang, Zheng, Shengrun
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container_issue Pt 7
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container_title Acta crystallographica. Section E, Structure reports online
container_volume 67
creator Shuai, Wenlin
Cai, Songliang
Zheng, Shengrun
description In the title compound, [Zn(C(4)H(3)N(2)O(2))(2)(H(2)O)(2)], the Zn(II) ion is situated on a twofold rotation axis and exhibits a distorted octa-hedral coordination configuration. The equatorial plane contains two cis-oriented bidentate 1H-imidazole-4-carboxyl-ate ligands and the axial positions are occupied by two coordinated water mol-ecules. In the crystal structure, inter-molecular O-H⋯O and N-H⋯O hydrogen bonds link the mol-ecules into a three-dimensional supra-molecular network. There are π-π inter-actions between the imidazole rings, with a centroid-to-centroid distance of 3.504 (3) Å.
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title Diaqua-bis-(1H-imidazole-4-carboxyl-ato-κN,O)zinc
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