{4-Hy-droxy-N'-[(2E,3Z)-4-oxido-4-phenyl-but-3-en-2-yl-idene]benzo-hydrazidato}dimethyl-tin(IV)
The Sn(IV) atom in the title compound, [Sn(CH(3))(2)(C(17)H(14)N(2)O(3))], is five-coordinated within a C(2)N(2)O donor set provided by the N,N,O-tridentate ligand and two methyl groups. The resultant coordination geometry is inter-mediate between trigonal-bipyramidal and square-pyramidal. In the cr...
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Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2011-07, Vol.67 (Pt 7), p.m965-m965 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | The Sn(IV) atom in the title compound, [Sn(CH(3))(2)(C(17)H(14)N(2)O(3))], is five-coordinated within a C(2)N(2)O donor set provided by the N,N,O-tridentate ligand and two methyl groups. The resultant coordination geometry is inter-mediate between trigonal-bipyramidal and square-pyramidal. In the crystal, supra-molecular zigzag chains propagating along the c- axis direction are mediated by O-H⋯O hydrogen bonds, and weak C-H⋯π inter-actions consolidate the packing. |
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ISSN: | 1600-5368 |
DOI: | 10.1107/S1600536811023506 |