Synthesis and Reactivity of Unique Heterocyclic Structures en Route to Substituted Diamines

Rhodium-catalyzed oxidative cyclization of allylic hydroxylamine-derived sulfamate esters furnishes a novel family of bicyclic aziridines that serve as functional precursors to substituted diamines. Investigations with the N4-Troc form of these heterocycles have led to manifold improvements in react...

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Veröffentlicht in:	Organic letters 2011-07, Vol.13 (13), p.3336-3339
Hauptverfasser:	Olson, David E, Maruniak, Autumn, Malhotra, Sushant, Trost, Barry M, Du Bois, J
Format:	Artikel
Sprache:	eng
Schlagworte:	Aziridines - chemistry Catalysis Diamines - chemistry Heterocyclic Compounds - chemical synthesis Molecular Structure Oxidation-Reduction Stereoisomerism
Online-Zugang:	Volltext
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