Chemical and Physicochemical Pretreatment of Lignocellulosic Biomass: A Review

Overcoming the recalcitrance (resistance of plant cell walls to deconstruction) of lignocellulosic biomass is a key step in the production of fuels and chemicals. The recalcitrance is due to the highly crystalline structure of cellulose which is embedded in a matrix of polymers-lignin and hemicellul...

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Veröffentlicht in:Enzyme Research 2011, Vol.2011 (2011), p.806-822
Hauptverfasser: Yau, Elizabeth, Brodeur, Gary, Badal, Kimberly, Collier, John, Ramachandran, K. B., Ramakrishnan, Subramanian
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container_end_page 822
container_issue 2011
container_start_page 806
container_title Enzyme Research
container_volume 2011
creator Yau, Elizabeth
Brodeur, Gary
Badal, Kimberly
Collier, John
Ramachandran, K. B.
Ramakrishnan, Subramanian
description Overcoming the recalcitrance (resistance of plant cell walls to deconstruction) of lignocellulosic biomass is a key step in the production of fuels and chemicals. The recalcitrance is due to the highly crystalline structure of cellulose which is embedded in a matrix of polymers-lignin and hemicellulose. The main goal of pretreatment is to overcome this recalcitrance, to separate the cellulose from the matrix polymers, and to make it more accessible for enzymatic hydrolysis. Reports have shown that pretreatment can improve sugar yields to higher than 90% theoretical yield for biomass such as wood, grasses, and corn. This paper reviews different leading pretreatment technologies along with their latest developments and highlights their advantages and disadvantages with respect to subsequent hydrolysis and fermentation. The effects of different technologies on the components of biomass (cellulose, hemicellulose, and lignin) are also reviewed with a focus on how the treatment greatly enhances enzymatic cellulose digestibility.
doi_str_mv 10.4061/2011/787532
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subjects Biomass
Cellulose
Hydrolysis
Lignin
Review
title Chemical and Physicochemical Pretreatment of Lignocellulosic Biomass: A Review
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