(R)-2-[1-(2,6-Dichloro-3,4,5-trimeth-oxy-benzo-yl)pyrrolidin-2-yl]-4,4,5,5-tetra-methyl-4,5-dihydro-1H-imidazole-1-oxyl 3-oxide

(R)-2-[1-(2,6-Dichloro-3,4,5-trimeth-oxy-benzo-yl)pyrrolidin-2-yl]-4,4,5,5-tetra-methyl-4,5-dihydro-1H-imidazole-1-oxyl 3-oxide

In the title compound, C(21)H(28)Cl(2)N(3)O(6), the nitronyl nitroxide ring displays a half-chair conformation, whereas the pyrrolidine ring has an envelope conformation. These two rings are twisted to each other with N-C-C-N torsion angles around the connecting C-C bond of 48.9 (6) and -127.0 (5)°....

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2011-04, Vol.67 (Pt 4), p.o985-o986
Hauptverfasser: Wang, Hai-Bo, Xiang, Zhuo, Jing, Lin-Lin, Tian, Min, Sun, Xiao-Li
Format: Artikel
Sprache:eng
Schlagworte:
Organic Papers
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page o986
container_issue Pt 4
container_start_page o985
container_title Acta crystallographica. Section E, Structure reports online
container_volume 67
creator Wang, Hai-Bo
Xiang, Zhuo
Jing, Lin-Lin
Tian, Min
Sun, Xiao-Li
description In the title compound, C(21)H(28)Cl(2)N(3)O(6), the nitronyl nitroxide ring displays a half-chair conformation, whereas the pyrrolidine ring has an envelope conformation. These two rings are twisted to each other with N-C-C-N torsion angles around the connecting C-C bond of 48.9 (6) and -127.0 (5)°. The benzene ring is nearly perpendicular to the pyrrolidine ring, with torsion angles around the connecting C-C bond of 86.3 (6) and -97.7 (6)°. The crystal structure is stabilized by C-H⋯O and C-H⋯π hydrogen bonds, which build up a three-dimensional network.
doi_str_mv 10.1107/S1600536811010270
format Article
fullrecord <record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_3099877</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>877404378</sourcerecordid><originalsourceid>FETCH-LOGICAL-p180t-e45fe355b42000387a8ad5c8170e38bf42782cfc59f431430581d2750c889a353</originalsourceid><addsrcrecordid>eNpVkMlKxEAQhhtB3B_Ai3jTgSmt3tI9F0HGFQTB5SQSOknHaemkxyQjxouvbgcX9FRU1f9_tRCyTfGAUlSHtzRBlDzRMaPIFC6RtaEEQ22VrLftMyJNFKMrZJVRJQUTfI187N-MgMEDhX02TuDE5TMfmgB8LMYSusZVtptBeOshs_V7gN6P5n3TBO8KV0dj7x9BDNpBbbvGwGDoPQz2ws36IsLoBbjKFeY9eAt0oPldHoMr7CZZLo1v7dZ33CD3Z6d30wu4uj6_nB5fwZxq7MAKWVouZSYYInKtjDaFzDVVaLnOSsGUZnmZy0kpOBUcpaYFUxJzrSeGS75Bjr6480VW2SK3ddzVp_N4oGn6NBiX_u_UbpY-hdeU42SilYqAvW9AE14Wtu3SyrW59d7UNizaNGoECq50VO78HfU74-fp_BOutH6x</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>877404378</pqid></control><display><type>article</type><title>(R)-2-[1-(2,6-Dichloro-3,4,5-trimeth-oxy-benzo-yl)pyrrolidin-2-yl]-4,4,5,5-tetra-methyl-4,5-dihydro-1H-imidazole-1-oxyl 3-oxide</title><source>DOAJ Directory of Open Access Journals</source><source>PubMed Central</source><source>Free Full-Text Journals in Chemistry</source><source>PubMed Central Open Access</source><creator>Wang, Hai-Bo ; Xiang, Zhuo ; Jing, Lin-Lin ; Tian, Min ; Sun, Xiao-Li</creator><creatorcontrib>Wang, Hai-Bo ; Xiang, Zhuo ; Jing, Lin-Lin ; Tian, Min ; Sun, Xiao-Li</creatorcontrib><description>In the title compound, C(21)H(28)Cl(2)N(3)O(6), the nitronyl nitroxide ring displays a half-chair conformation, whereas the pyrrolidine ring has an envelope conformation. These two rings are twisted to each other with N-C-C-N torsion angles around the connecting C-C bond of 48.9 (6) and -127.0 (5)°. The benzene ring is nearly perpendicular to the pyrrolidine ring, with torsion angles around the connecting C-C bond of 86.3 (6) and -97.7 (6)°. The crystal structure is stabilized by C-H⋯O and C-H⋯π hydrogen bonds, which build up a three-dimensional network.</description><identifier>EISSN: 1600-5368</identifier><identifier>DOI: 10.1107/S1600536811010270</identifier><identifier>PMID: 21754243</identifier><language>eng</language><publisher>United States: International Union of Crystallography</publisher><subject>Organic Papers</subject><ispartof>Acta crystallographica. Section E, Structure reports online, 2011-04, Vol.67 (Pt 4), p.o985-o986</ispartof><rights>Wang et al. 2011 2011</rights><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099877/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099877/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,723,776,780,860,881,27901,27902,53766,53768</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/21754243$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Wang, Hai-Bo</creatorcontrib><creatorcontrib>Xiang, Zhuo</creatorcontrib><creatorcontrib>Jing, Lin-Lin</creatorcontrib><creatorcontrib>Tian, Min</creatorcontrib><creatorcontrib>Sun, Xiao-Li</creatorcontrib><title>(R)-2-[1-(2,6-Dichloro-3,4,5-trimeth-oxy-benzo-yl)pyrrolidin-2-yl]-4,4,5,5-tetra-methyl-4,5-dihydro-1H-imidazole-1-oxyl 3-oxide</title><title>Acta crystallographica. Section E, Structure reports online</title><addtitle>Acta Crystallogr Sect E Struct Rep Online</addtitle><description>In the title compound, C(21)H(28)Cl(2)N(3)O(6), the nitronyl nitroxide ring displays a half-chair conformation, whereas the pyrrolidine ring has an envelope conformation. These two rings are twisted to each other with N-C-C-N torsion angles around the connecting C-C bond of 48.9 (6) and -127.0 (5)°. The benzene ring is nearly perpendicular to the pyrrolidine ring, with torsion angles around the connecting C-C bond of 86.3 (6) and -97.7 (6)°. The crystal structure is stabilized by C-H⋯O and C-H⋯π hydrogen bonds, which build up a three-dimensional network.</description><subject>Organic Papers</subject><issn>1600-5368</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNpVkMlKxEAQhhtB3B_Ai3jTgSmt3tI9F0HGFQTB5SQSOknHaemkxyQjxouvbgcX9FRU1f9_tRCyTfGAUlSHtzRBlDzRMaPIFC6RtaEEQ22VrLftMyJNFKMrZJVRJQUTfI187N-MgMEDhX02TuDE5TMfmgB8LMYSusZVtptBeOshs_V7gN6P5n3TBO8KV0dj7x9BDNpBbbvGwGDoPQz2ws36IsLoBbjKFeY9eAt0oPldHoMr7CZZLo1v7dZ33CD3Z6d30wu4uj6_nB5fwZxq7MAKWVouZSYYInKtjDaFzDVVaLnOSsGUZnmZy0kpOBUcpaYFUxJzrSeGS75Bjr6480VW2SK3ddzVp_N4oGn6NBiX_u_UbpY-hdeU42SilYqAvW9AE14Wtu3SyrW59d7UNizaNGoECq50VO78HfU74-fp_BOutH6x</recordid><startdate>201104</startdate><enddate>201104</enddate><creator>Wang, Hai-Bo</creator><creator>Xiang, Zhuo</creator><creator>Jing, Lin-Lin</creator><creator>Tian, Min</creator><creator>Sun, Xiao-Li</creator><general>International Union of Crystallography</general><scope>NPM</scope><scope>7X8</scope><scope>5PM</scope></search><sort><creationdate>201104</creationdate><title>(R)-2-[1-(2,6-Dichloro-3,4,5-trimeth-oxy-benzo-yl)pyrrolidin-2-yl]-4,4,5,5-tetra-methyl-4,5-dihydro-1H-imidazole-1-oxyl 3-oxide</title><author>Wang, Hai-Bo ; Xiang, Zhuo ; Jing, Lin-Lin ; Tian, Min ; Sun, Xiao-Li</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p180t-e45fe355b42000387a8ad5c8170e38bf42782cfc59f431430581d2750c889a353</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Organic Papers</topic><toplevel>online_resources</toplevel><creatorcontrib>Wang, Hai-Bo</creatorcontrib><creatorcontrib>Xiang, Zhuo</creatorcontrib><creatorcontrib>Jing, Lin-Lin</creatorcontrib><creatorcontrib>Tian, Min</creatorcontrib><creatorcontrib>Sun, Xiao-Li</creatorcontrib><collection>PubMed</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Acta crystallographica. Section E, Structure reports online</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Hai-Bo</au><au>Xiang, Zhuo</au><au>Jing, Lin-Lin</au><au>Tian, Min</au><au>Sun, Xiao-Li</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>(R)-2-[1-(2,6-Dichloro-3,4,5-trimeth-oxy-benzo-yl)pyrrolidin-2-yl]-4,4,5,5-tetra-methyl-4,5-dihydro-1H-imidazole-1-oxyl 3-oxide</atitle><jtitle>Acta crystallographica. Section E, Structure reports online</jtitle><addtitle>Acta Crystallogr Sect E Struct Rep Online</addtitle><date>2011-04</date><risdate>2011</risdate><volume>67</volume><issue>Pt 4</issue><spage>o985</spage><epage>o986</epage><pages>o985-o986</pages><eissn>1600-5368</eissn><abstract>In the title compound, C(21)H(28)Cl(2)N(3)O(6), the nitronyl nitroxide ring displays a half-chair conformation, whereas the pyrrolidine ring has an envelope conformation. These two rings are twisted to each other with N-C-C-N torsion angles around the connecting C-C bond of 48.9 (6) and -127.0 (5)°. The benzene ring is nearly perpendicular to the pyrrolidine ring, with torsion angles around the connecting C-C bond of 86.3 (6) and -97.7 (6)°. The crystal structure is stabilized by C-H⋯O and C-H⋯π hydrogen bonds, which build up a three-dimensional network.</abstract><cop>United States</cop><pub>International Union of Crystallography</pub><pmid>21754243</pmid><doi>10.1107/S1600536811010270</doi><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier EISSN: 1600-5368
ispartof Acta crystallographica. Section E, Structure reports online, 2011-04, Vol.67 (Pt 4), p.o985-o986
issn 1600-5368
language eng
recordid cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_3099877
source DOAJ Directory of Open Access Journals; PubMed Central; Free Full-Text Journals in Chemistry; PubMed Central Open Access
subjects Organic Papers
title (R)-2-[1-(2,6-Dichloro-3,4,5-trimeth-oxy-benzo-yl)pyrrolidin-2-yl]-4,4,5,5-tetra-methyl-4,5-dihydro-1H-imidazole-1-oxyl 3-oxide
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-10T09%3A04%3A20IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_pubme&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=(R)-2-%5B1-(2,6-Dichloro-3,4,5-trimeth-oxy-benzo-yl)pyrrolidin-2-yl%5D-4,4,5,5-tetra-methyl-4,5-dihydro-1H-imidazole-1-oxyl%203-oxide&rft.jtitle=Acta%20crystallographica.%20Section%20E,%20Structure%20reports%20online&rft.au=Wang,%20Hai-Bo&rft.date=2011-04&rft.volume=67&rft.issue=Pt%204&rft.spage=o985&rft.epage=o986&rft.pages=o985-o986&rft.eissn=1600-5368&rft_id=info:doi/10.1107/S1600536811010270&rft_dat=%3Cproquest_pubme%3E877404378%3C/proquest_pubme%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=877404378&rft_id=info:pmid/21754243&rfr_iscdi=true