Palladium-Catalyzed 1,1-Aryloxygenation of Terminal Olefins

Palladium-Catalyzed 1,1-Aryloxygenation of Terminal Olefins

This paper describes the 1,1-arylacetoxylation of diverse α-olefins using organostannanes and hypervalent iodine oxidants. The reaction provides a convergent approach for generating a C−C and a C−O bond as well as a new stereocenter in a single catalytic transformation.

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Veröffentlicht in:Organic letters 2011-03, Vol.13 (5), p.1076-1079
Hauptverfasser: Satterfield, Andrew D, Kubota, Asako, Sanford, Melanie S
Format: Artikel
Sprache:eng
Schlagworte:
Alkenes - chemistry
Catalysis
Iodine - chemistry
Organotin Compounds - chemistry
Oxidants - chemistry
Palladium - chemistry
Stereoisomerism
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Zusammenfassung:This paper describes the 1,1-arylacetoxylation of diverse α-olefins using organostannanes and hypervalent iodine oxidants. The reaction provides a convergent approach for generating a C−C and a C−O bond as well as a new stereocenter in a single catalytic transformation.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol103121r