4-Methyl-N-[(E)-4-methyl-1-(4-methyl-phenyl-sulfon-yl)-1,2-dihydropyridin-2-yl-idene]benzene-sulfonamide

4-Methyl-N-[(E)-4-methyl-1-(4-methyl-phenyl-sulfon-yl)-1,2-dihydropyridin-2-yl-idene]benzene-sulfonamide

The reaction of 2-(amino-meth-yl)pyridine and 4-toluene-sulfonyl chloride in CH(2)Cl(2) at pH 8 led to the title compound, C(20)H(20)N(2)O(4)S(2). The aromatic rings are almost perpendicular to each other and the dihedral angles between the aromatic ring planes are 74.33 (9) (central pyridine versus...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2010-07, Vol.66 (Pt 8), p.o1891-o1891
Hauptverfasser: Tabatabaee, Masoumeh, Ghassemzadeh, Mitra, Hesami, Liela, Neumüller, Bernhard
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container_issue Pt 8
container_start_page o1891
container_title Acta crystallographica. Section E, Structure reports online
container_volume 66
creator Tabatabaee, Masoumeh
Ghassemzadeh, Mitra
Hesami, Liela
Neumüller, Bernhard
description The reaction of 2-(amino-meth-yl)pyridine and 4-toluene-sulfonyl chloride in CH(2)Cl(2) at pH 8 led to the title compound, C(20)H(20)N(2)O(4)S(2). The aromatic rings are almost perpendicular to each other and the dihedral angles between the aromatic ring planes are 74.33 (9) (central pyridine versus benzene ring of the tosyl group bonded to the imine functionality), 73.77 (6) (pyridine versus benzene ring of the tosyl group bonded to pyridinic N atom) and 79.83 (9)° (benzene rings of tosyl groups). In the crystal structure, inter-molecular aromatic π-π stacking inter-actions [centroid-centroid separation = 3.6274 (14) Å] help to consolidate the packing.
doi_str_mv 10.1107/S1600536810025158
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title 4-Methyl-N-[(E)-4-methyl-1-(4-methyl-phenyl-sulfon-yl)-1,2-dihydropyridin-2-yl-idene]benzene-sulfonamide
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