A new coordination tetra­mer of copper(I) iodide and benzyl­dimethyl­amine: tetra-μ3-iodido-tetra­kis[(benzyl­dimethyl­amine-κN)copper(I)]

A new coordination tetra­mer of copper(I) iodide and benzyl­dimethyl­amine: tetra-μ3-iodido-tetra­kis[(benzyl­dimethyl­amine-κN)copper(I)]

The title compound, [Cu 4 I 4 (C 9 H 13 N) 4 ], has a distorted cubane-like [Cu 4 I 4 ] core structure. Each Cu I atom is tetra­hedrally coordinated by three I atoms and one N atom of an benzyl­dimethyl­amine ligand. Each I atom acts as a μ 3 -ligand, linking three Cu I atoms. The Cu—I bond distance...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2009-07, Vol.65 (Pt 8), p.m906-m906
Hauptverfasser: Yang, Shuying, Li, Yuebao, Cui, Yujie, Pan, Jianguo
Format: Artikel
Sprache:eng
Schlagworte:
Metal-Organic Papers
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The title compound, [Cu 4 I 4 (C 9 H 13 N) 4 ], has a distorted cubane-like [Cu 4 I 4 ] core structure. Each Cu I atom is tetra­hedrally coordinated by three I atoms and one N atom of an benzyl­dimethyl­amine ligand. Each I atom acts as a μ 3 -ligand, linking three Cu I atoms. The Cu—I bond distances vary between 2.6328 (7) and 2.7121 (6) Å, while the Cu—N bond distances vary between 2.107 (3) and 2.122 (3) Å.
ISSN:1600-5368
DOI:10.1107/S1600536809026208