Dicarbon-yl(η-cyclo-penta-dien-yl)bis-(trimethyl-phosphine)molybdenum(II) trifluoro-methane-sulfonate

Dicarbon-yl(η-cyclo-penta-dien-yl)bis-(trimethyl-phosphine)molybdenum(II) trifluoro-methane-sulfonate

In the title compound, [Mo(C(5)H(5))(CO)(2)(C(3)H(9)P)(2)]CF(3)SO(3), the cationic complex displays a classical four-legged piano-stool square-pyramidal geometry with a trans configuration of the basal ligands around the Mo atom. The cyclo-penta-dienyl (Cp) ligand occupies the apical position of the...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2008-10, Vol.64 (Pt 11), p.m1401-m1401
Hauptverfasser: Jali, Samuel, Friedrich, Holger B, Bala, Muhammad D
Format: Artikel
Sprache:eng
Schlagworte:
Metal-Organic Papers
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Beschreibung
Zusammenfassung:In the title compound, [Mo(C(5)H(5))(CO)(2)(C(3)H(9)P)(2)]CF(3)SO(3), the cationic complex displays a classical four-legged piano-stool square-pyramidal geometry with a trans configuration of the basal ligands around the Mo atom. The cyclo-penta-dienyl (Cp) ligand occupies the apical position of the piano-stool configuration. The average Mo-P bond length of the two trans PMe(3) ligands is 2.474 (5) Å and the Mo-Cp centroid distance is 2.003 (2) Å.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536808032662