Synthesis of Heterogeneous Li4Ti5O12 Nanostructured Anodes with Long-Term Cycle Stability
The 0D-1D Lithium titanate (Li 4 Ti 5 O 12 ) heterogeneous nanostructures were synthesized through the solvothermal reaction using lithium hydroxide monohydrate (Li(OH)·H 2 O) and protonated trititanate (H 2 Ti 3 O 7 ) nanowires as the templates in an ethanol/water mixed solvent with subsequent heat...
Gespeichert in:
| Veröffentlicht in: | Nanoscale research letters 2010-10, Vol.5 (10), p.1585-1589 |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1589 |
|---|---|
| container_issue | 10 |
| container_start_page | 1585 |
| container_title | Nanoscale research letters |
| container_volume | 5 |
| creator | Lee, Duk Kyu Shim, Hyun-Woo An, Jae Sul Cho, Chin Moo Cho, In-Sun Hong, Kug Sun Kim, Dong-Wan |
| description | The 0D-1D Lithium titanate (Li
4
Ti
5
O
12
) heterogeneous nanostructures were synthesized through the solvothermal reaction using lithium hydroxide monohydrate (Li(OH)·H
2
O) and protonated trititanate (H
2
Ti
3
O
7
) nanowires as the templates in an ethanol/water mixed solvent with subsequent heat treatment. A scanning electron microscope (SEM) and a high resolution transmission electron microscope (HRTEM) were used to reveal that the Li
4
Ti
5
O
12
powders had 0D-1D heterogeneous nanostructures with nanoparticles (0D) on the surface of wires (1D). The composition of the mixed solvents and the volume ratio of ethanol modulated the primary particle size of the Li
4
Ti
5
O
12
nanoparticles. The Li
4
Ti
5
O
12
heterogeneous nanostructures exhibited good capacity retention of 125 mAh/g after 500 cycles at 1C and a superior high-rate performance of 114 mAh/g at 20C. |
| doi_str_mv | 10.1007/s11671-010-9680-4 |
| format | Article |
| fullrecord | <record><control><sourceid>pubmedcentral_cross</sourceid><recordid>TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_2956043</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>pubmedcentral_primary_oai_pubmedcentral_nih_gov_2956043</sourcerecordid><originalsourceid>FETCH-LOGICAL-c316t-3b1a1424b648379568f0a1f7462f3943fa6f9229a5b8b68f2812e44890adb70b3</originalsourceid><addsrcrecordid>eNp9kM1KAzEUhYMo_j-Au7xANDfJJDMboRT_oNhFK-gqZKaZNtImJckofXsjFcGNq3Ph3HMu90PoCug1UKpuEoBUQChQ0siaEnGATqGqJGFKvh6WueFAVKX4CTpL6Z1SoaiSx-iEQVEp1Sl6m-18XtnkEg49frTZxrC03oYh4YkTc1dNgeFn40PKcejyEO0Cj3xY2IQ_XV7hSfBLMrdxg8e7bm3xLJvWrV3eXaCj3qyTvfzRc_RyfzcfP5LJ9OFpPJqQjoPMhLdgQDDRSlFz1VSy7qmBXgnJet4I3hvZN4w1pmrrtpisBmaFqBtqFq2iLT9Ht_ve7dBu7KKzPkez1tvoNibudDBO_3W8W-ll-NCsHKOClwLYF3QxpBRt_5sFqr856z1nXTjrb85alAzbZ1LZ9Usb9XsYoi9__hP6At74f5U</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Synthesis of Heterogeneous Li4Ti5O12 Nanostructured Anodes with Long-Term Cycle Stability</title><source>PubMed Central Free</source><source>Directory of Open Access Journals</source><source>PubMed Central Open Access</source><source>Free Full-Text Journals in Chemistry</source><source>EZB Electronic Journals Library</source><creator>Lee, Duk Kyu ; Shim, Hyun-Woo ; An, Jae Sul ; Cho, Chin Moo ; Cho, In-Sun ; Hong, Kug Sun ; Kim, Dong-Wan</creator><creatorcontrib>Lee, Duk Kyu ; Shim, Hyun-Woo ; An, Jae Sul ; Cho, Chin Moo ; Cho, In-Sun ; Hong, Kug Sun ; Kim, Dong-Wan</creatorcontrib><description>The 0D-1D Lithium titanate (Li
4
Ti
5
O
12
) heterogeneous nanostructures were synthesized through the solvothermal reaction using lithium hydroxide monohydrate (Li(OH)·H
2
O) and protonated trititanate (H
2
Ti
3
O
7
) nanowires as the templates in an ethanol/water mixed solvent with subsequent heat treatment. A scanning electron microscope (SEM) and a high resolution transmission electron microscope (HRTEM) were used to reveal that the Li
4
Ti
5
O
12
powders had 0D-1D heterogeneous nanostructures with nanoparticles (0D) on the surface of wires (1D). The composition of the mixed solvents and the volume ratio of ethanol modulated the primary particle size of the Li
4
Ti
5
O
12
nanoparticles. The Li
4
Ti
5
O
12
heterogeneous nanostructures exhibited good capacity retention of 125 mAh/g after 500 cycles at 1C and a superior high-rate performance of 114 mAh/g at 20C.</description><identifier>ISSN: 1931-7573</identifier><identifier>EISSN: 1556-276X</identifier><identifier>DOI: 10.1007/s11671-010-9680-4</identifier><identifier>PMID: 21076667</identifier><language>eng</language><publisher>New York: Springer New York</publisher><subject>Chemistry and Materials Science ; Materials Science ; Molecular Medicine ; Nano Express ; Nanochemistry ; Nanoscale Science and Technology ; Nanotechnology ; Nanotechnology and Microengineering</subject><ispartof>Nanoscale research letters, 2010-10, Vol.5 (10), p.1585-1589</ispartof><rights>The Author(s) 2010</rights><rights>Copyright © 2010 The Author(s) 2010 The Author(s)</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-3b1a1424b648379568f0a1f7462f3943fa6f9229a5b8b68f2812e44890adb70b3</citedby><cites>FETCH-LOGICAL-c316t-3b1a1424b648379568f0a1f7462f3943fa6f9229a5b8b68f2812e44890adb70b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC2956043/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC2956043/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,315,728,781,785,865,886,27926,27927,53793,53795</link.rule.ids></links><search><creatorcontrib>Lee, Duk Kyu</creatorcontrib><creatorcontrib>Shim, Hyun-Woo</creatorcontrib><creatorcontrib>An, Jae Sul</creatorcontrib><creatorcontrib>Cho, Chin Moo</creatorcontrib><creatorcontrib>Cho, In-Sun</creatorcontrib><creatorcontrib>Hong, Kug Sun</creatorcontrib><creatorcontrib>Kim, Dong-Wan</creatorcontrib><title>Synthesis of Heterogeneous Li4Ti5O12 Nanostructured Anodes with Long-Term Cycle Stability</title><title>Nanoscale research letters</title><addtitle>Nanoscale Res Lett</addtitle><description>The 0D-1D Lithium titanate (Li
4
Ti
5
O
12
) heterogeneous nanostructures were synthesized through the solvothermal reaction using lithium hydroxide monohydrate (Li(OH)·H
2
O) and protonated trititanate (H
2
Ti
3
O
7
) nanowires as the templates in an ethanol/water mixed solvent with subsequent heat treatment. A scanning electron microscope (SEM) and a high resolution transmission electron microscope (HRTEM) were used to reveal that the Li
4
Ti
5
O
12
powders had 0D-1D heterogeneous nanostructures with nanoparticles (0D) on the surface of wires (1D). The composition of the mixed solvents and the volume ratio of ethanol modulated the primary particle size of the Li
4
Ti
5
O
12
nanoparticles. The Li
4
Ti
5
O
12
heterogeneous nanostructures exhibited good capacity retention of 125 mAh/g after 500 cycles at 1C and a superior high-rate performance of 114 mAh/g at 20C.</description><subject>Chemistry and Materials Science</subject><subject>Materials Science</subject><subject>Molecular Medicine</subject><subject>Nano Express</subject><subject>Nanochemistry</subject><subject>Nanoscale Science and Technology</subject><subject>Nanotechnology</subject><subject>Nanotechnology and Microengineering</subject><issn>1931-7573</issn><issn>1556-276X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><sourceid>C6C</sourceid><recordid>eNp9kM1KAzEUhYMo_j-Au7xANDfJJDMboRT_oNhFK-gqZKaZNtImJckofXsjFcGNq3Ph3HMu90PoCug1UKpuEoBUQChQ0siaEnGATqGqJGFKvh6WueFAVKX4CTpL6Z1SoaiSx-iEQVEp1Sl6m-18XtnkEg49frTZxrC03oYh4YkTc1dNgeFn40PKcejyEO0Cj3xY2IQ_XV7hSfBLMrdxg8e7bm3xLJvWrV3eXaCj3qyTvfzRc_RyfzcfP5LJ9OFpPJqQjoPMhLdgQDDRSlFz1VSy7qmBXgnJet4I3hvZN4w1pmrrtpisBmaFqBtqFq2iLT9Ht_ve7dBu7KKzPkez1tvoNibudDBO_3W8W-ll-NCsHKOClwLYF3QxpBRt_5sFqr856z1nXTjrb85alAzbZ1LZ9Usb9XsYoi9__hP6At74f5U</recordid><startdate>20101001</startdate><enddate>20101001</enddate><creator>Lee, Duk Kyu</creator><creator>Shim, Hyun-Woo</creator><creator>An, Jae Sul</creator><creator>Cho, Chin Moo</creator><creator>Cho, In-Sun</creator><creator>Hong, Kug Sun</creator><creator>Kim, Dong-Wan</creator><general>Springer New York</general><general>Springer</general><scope>C6C</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>5PM</scope></search><sort><creationdate>20101001</creationdate><title>Synthesis of Heterogeneous Li4Ti5O12 Nanostructured Anodes with Long-Term Cycle Stability</title><author>Lee, Duk Kyu ; Shim, Hyun-Woo ; An, Jae Sul ; Cho, Chin Moo ; Cho, In-Sun ; Hong, Kug Sun ; Kim, Dong-Wan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-3b1a1424b648379568f0a1f7462f3943fa6f9229a5b8b68f2812e44890adb70b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Chemistry and Materials Science</topic><topic>Materials Science</topic><topic>Molecular Medicine</topic><topic>Nano Express</topic><topic>Nanochemistry</topic><topic>Nanoscale Science and Technology</topic><topic>Nanotechnology</topic><topic>Nanotechnology and Microengineering</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lee, Duk Kyu</creatorcontrib><creatorcontrib>Shim, Hyun-Woo</creatorcontrib><creatorcontrib>An, Jae Sul</creatorcontrib><creatorcontrib>Cho, Chin Moo</creatorcontrib><creatorcontrib>Cho, In-Sun</creatorcontrib><creatorcontrib>Hong, Kug Sun</creatorcontrib><creatorcontrib>Kim, Dong-Wan</creatorcontrib><collection>Springer Nature OA Free Journals</collection><collection>CrossRef</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Nanoscale research letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lee, Duk Kyu</au><au>Shim, Hyun-Woo</au><au>An, Jae Sul</au><au>Cho, Chin Moo</au><au>Cho, In-Sun</au><au>Hong, Kug Sun</au><au>Kim, Dong-Wan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of Heterogeneous Li4Ti5O12 Nanostructured Anodes with Long-Term Cycle Stability</atitle><jtitle>Nanoscale research letters</jtitle><stitle>Nanoscale Res Lett</stitle><date>2010-10-01</date><risdate>2010</risdate><volume>5</volume><issue>10</issue><spage>1585</spage><epage>1589</epage><pages>1585-1589</pages><issn>1931-7573</issn><eissn>1556-276X</eissn><abstract>The 0D-1D Lithium titanate (Li
4
Ti
5
O
12
) heterogeneous nanostructures were synthesized through the solvothermal reaction using lithium hydroxide monohydrate (Li(OH)·H
2
O) and protonated trititanate (H
2
Ti
3
O
7
) nanowires as the templates in an ethanol/water mixed solvent with subsequent heat treatment. A scanning electron microscope (SEM) and a high resolution transmission electron microscope (HRTEM) were used to reveal that the Li
4
Ti
5
O
12
powders had 0D-1D heterogeneous nanostructures with nanoparticles (0D) on the surface of wires (1D). The composition of the mixed solvents and the volume ratio of ethanol modulated the primary particle size of the Li
4
Ti
5
O
12
nanoparticles. The Li
4
Ti
5
O
12
heterogeneous nanostructures exhibited good capacity retention of 125 mAh/g after 500 cycles at 1C and a superior high-rate performance of 114 mAh/g at 20C.</abstract><cop>New York</cop><pub>Springer New York</pub><pmid>21076667</pmid><doi>10.1007/s11671-010-9680-4</doi><tpages>5</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1931-7573 |
| ispartof | Nanoscale research letters, 2010-10, Vol.5 (10), p.1585-1589 |
| issn | 1931-7573 1556-276X |
| language | eng |
| recordid | cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_2956043 |
| source | PubMed Central Free; Directory of Open Access Journals; PubMed Central Open Access; Free Full-Text Journals in Chemistry; EZB Electronic Journals Library |
| subjects | Chemistry and Materials Science Materials Science Molecular Medicine Nano Express Nanochemistry Nanoscale Science and Technology Nanotechnology Nanotechnology and Microengineering |
| title | Synthesis of Heterogeneous Li4Ti5O12 Nanostructured Anodes with Long-Term Cycle Stability |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-17T17%3A38%3A53IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-pubmedcentral_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20of%20Heterogeneous%20Li4Ti5O12%20Nanostructured%20Anodes%20with%20Long-Term%20Cycle%20Stability&rft.jtitle=Nanoscale%20research%20letters&rft.au=Lee,%20Duk%20Kyu&rft.date=2010-10-01&rft.volume=5&rft.issue=10&rft.spage=1585&rft.epage=1589&rft.pages=1585-1589&rft.issn=1931-7573&rft.eissn=1556-276X&rft_id=info:doi/10.1007/s11671-010-9680-4&rft_dat=%3Cpubmedcentral_cross%3Epubmedcentral_primary_oai_pubmedcentral_nih_gov_2956043%3C/pubmedcentral_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/21076667&rfr_iscdi=true |