Tailored composite polymer-metal nanoparticles by miniemulsion polymerization and thiol-ene functionalization
A simple and modular synthetic approach, based on miniemulsion polymerization, has been developed for the fabrication of composite polymer-metal nanoparticle materials. The procedure produces well-defined composite structures consisting of gold, silver, or MnFe₂O₄ nanoparticles (~10 nm in diameter)...
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| Veröffentlicht in: | Journal of polymer science. Part A, Polymer chemistry Polymer chemistry, 2010-04, Vol.48 (7), p.1594-1606 |
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| container_end_page | 1606 |
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| container_issue | 7 |
| container_start_page | 1594 |
| container_title | Journal of polymer science. Part A, Polymer chemistry |
| container_volume | 48 |
| creator | van Berkel, Kim Y Hawker, Craig J |
| description | A simple and modular synthetic approach, based on miniemulsion polymerization, has been developed for the fabrication of composite polymer-metal nanoparticle materials. The procedure produces well-defined composite structures consisting of gold, silver, or MnFe₂O₄ nanoparticles (~10 nm in diameter) encapsulated within larger spherical nanoparticles of poly(divinylbenzene) (~100 nm in diameter). This methodology readily permits the incorporation of multiple metal domains into a single polymeric particle, while still preserving the useful optical and magnetic properties of the metal nanoparticles. The morphology of the composite particles is retained upon increasing the inorganic content and also upon redispersion in organic solvents. Finally, the ability to tailor the surface chemistry of the composite nanoparticles and incorporate steric stabilizing groups using simple thiol-ene chemistry is demonstrated. |
| doi_str_mv | 10.1002/pola.23917 |
| format | Article |
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The procedure produces well-defined composite structures consisting of gold, silver, or MnFe₂O₄ nanoparticles (~10 nm in diameter) encapsulated within larger spherical nanoparticles of poly(divinylbenzene) (~100 nm in diameter). This methodology readily permits the incorporation of multiple metal domains into a single polymeric particle, while still preserving the useful optical and magnetic properties of the metal nanoparticles. The morphology of the composite particles is retained upon increasing the inorganic content and also upon redispersion in organic solvents. Finally, the ability to tailor the surface chemistry of the composite nanoparticles and incorporate steric stabilizing groups using simple thiol-ene chemistry is demonstrated.</description><identifier>ISSN: 0887-624X</identifier><identifier>ISSN: 1099-0518</identifier><identifier>EISSN: 1099-0518</identifier><identifier>DOI: 10.1002/pola.23917</identifier><identifier>PMID: 20657708</identifier><identifier>CODEN: JPLCAT</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Applied sciences ; composite nanoparticles ; Composite structures ; Composites ; core-shell polymers ; emulsion polymerization ; Encapsulation ; Exact sciences and technology ; Forms of application and semi-finished materials ; gold nanoparticles ; gold nanorods ; hybrid nanoparticles ; Magnetic properties ; miniemulsion polymerization ; nanocomposites ; Nanoparticles ; nanotechnology ; Optical properties ; Particulate composites ; Polymer industry, paints, wood ; Polymerization ; silver nanoparticles ; Surface chemistry ; Technology of polymers ; thiol-ene</subject><ispartof>Journal of polymer science. 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Part A, Polymer chemistry</title><addtitle>J. Polym. Sci. A Polym. Chem</addtitle><description>A simple and modular synthetic approach, based on miniemulsion polymerization, has been developed for the fabrication of composite polymer-metal nanoparticle materials. The procedure produces well-defined composite structures consisting of gold, silver, or MnFe₂O₄ nanoparticles (~10 nm in diameter) encapsulated within larger spherical nanoparticles of poly(divinylbenzene) (~100 nm in diameter). This methodology readily permits the incorporation of multiple metal domains into a single polymeric particle, while still preserving the useful optical and magnetic properties of the metal nanoparticles. The morphology of the composite particles is retained upon increasing the inorganic content and also upon redispersion in organic solvents. Finally, the ability to tailor the surface chemistry of the composite nanoparticles and incorporate steric stabilizing groups using simple thiol-ene chemistry is demonstrated.</description><subject>Applied sciences</subject><subject>composite nanoparticles</subject><subject>Composite structures</subject><subject>Composites</subject><subject>core-shell polymers</subject><subject>emulsion polymerization</subject><subject>Encapsulation</subject><subject>Exact sciences and technology</subject><subject>Forms of application and semi-finished materials</subject><subject>gold nanoparticles</subject><subject>gold nanorods</subject><subject>hybrid nanoparticles</subject><subject>Magnetic properties</subject><subject>miniemulsion polymerization</subject><subject>nanocomposites</subject><subject>Nanoparticles</subject><subject>nanotechnology</subject><subject>Optical properties</subject><subject>Particulate composites</subject><subject>Polymer industry, paints, wood</subject><subject>Polymerization</subject><subject>silver nanoparticles</subject><subject>Surface chemistry</subject><subject>Technology of polymers</subject><subject>thiol-ene</subject><issn>0887-624X</issn><issn>1099-0518</issn><issn>1099-0518</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNp9kU9v1DAQxSMEokvhwgeAXBAIKWXsJLZzQaoWaJFWFNEWuFmzttMaHDvYWWD59CTsH-DSkzV-v3kzo5dlDwkcEQD6og8Oj2jZEH4rmxFomgJqIm5nMxCCF4xWnw-yeyl9ARi1WtzNDiiwmnMQs6y7QOtCNDpXoetDsoPJR791Z2LRmQFd7tGHHuNglTMpX67zznprupVLNvgda3_hMJXodT5c2-AK403erryavtFt9fvZnRZdMg-272F2-eb1xfy0WJydvJ0fLwrFCPCiYctGI6moXpLGEATKgDEgokUoaw6sLTVWmleC6qrSmmljxnMqpVremFqUh9nLjW-_WnZGK-OHiE720XYY1zKglf8r3l7Lq_Bd0gZERdlo8HRrEMO3lUmD7GxSxjn0JqySbIAwJqAkI_nsRpIIygijgk2mzzeoiiGlaNr9QgTklKSckpR_khzhR_-esEd30Y3Aky2ASaFrI3pl01-O1gB1DSNHNtwP68z6hpHy_dnieDe82PTYNJif-x6MXyXjJa_lp3cn8ryZzz98fHUqp10eb_gWg8SrOO5xeU6BlGNm0BDBy99B69Ij</recordid><startdate>20100401</startdate><enddate>20100401</enddate><creator>van Berkel, Kim Y</creator><creator>Hawker, Craig J</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><scope>FBQ</scope><scope>BSCLL</scope><scope>IQODW</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><scope>5PM</scope></search><sort><creationdate>20100401</creationdate><title>Tailored composite polymer-metal nanoparticles by miniemulsion polymerization and thiol-ene functionalization</title><author>van Berkel, Kim Y ; Hawker, Craig J</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c6107-96b9da142db19e1a026066018fa035706f3da4d7482d44dd6dee7704ccf79e583</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Applied sciences</topic><topic>composite nanoparticles</topic><topic>Composite structures</topic><topic>Composites</topic><topic>core-shell polymers</topic><topic>emulsion polymerization</topic><topic>Encapsulation</topic><topic>Exact sciences and technology</topic><topic>Forms of application and semi-finished materials</topic><topic>gold nanoparticles</topic><topic>gold nanorods</topic><topic>hybrid nanoparticles</topic><topic>Magnetic properties</topic><topic>miniemulsion polymerization</topic><topic>nanocomposites</topic><topic>Nanoparticles</topic><topic>nanotechnology</topic><topic>Optical properties</topic><topic>Particulate composites</topic><topic>Polymer industry, paints, wood</topic><topic>Polymerization</topic><topic>silver nanoparticles</topic><topic>Surface chemistry</topic><topic>Technology of polymers</topic><topic>thiol-ene</topic><toplevel>online_resources</toplevel><creatorcontrib>van Berkel, Kim Y</creatorcontrib><creatorcontrib>Hawker, Craig J</creatorcontrib><collection>AGRIS</collection><collection>Istex</collection><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Journal of polymer science. 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| source | Wiley Online Library All Journals |
| subjects | Applied sciences composite nanoparticles Composite structures Composites core-shell polymers emulsion polymerization Encapsulation Exact sciences and technology Forms of application and semi-finished materials gold nanoparticles gold nanorods hybrid nanoparticles Magnetic properties miniemulsion polymerization nanocomposites Nanoparticles nanotechnology Optical properties Particulate composites Polymer industry, paints, wood Polymerization silver nanoparticles Surface chemistry Technology of polymers thiol-ene |
| title | Tailored composite polymer-metal nanoparticles by miniemulsion polymerization and thiol-ene functionalization |
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