Polymer track membranes for atmospheric pressure field extraction of ions from liquid solutions

An approach to the generation of gas phase ions by field extraction from liquid solutions has been investigated. The method uses a polymer membrane with nano-size channels as an interface between the liquid and the atmospheric pressure gas. Ions are produced by dissociation in the polar solvent and...

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Veröffentlicht in:Journal of electrostatics 2010-02, Vol.68 (1), p.96-100
Hauptverfasser: Balakin, A.A., Buido, E.A., Markin, M.I., Novikova, L.I., Baldwin, M.A.
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container_end_page 100
container_issue 1
container_start_page 96
container_title Journal of electrostatics
container_volume 68
creator Balakin, A.A.
Buido, E.A.
Markin, M.I.
Novikova, L.I.
Baldwin, M.A.
description An approach to the generation of gas phase ions by field extraction from liquid solutions has been investigated. The method uses a polymer membrane with nano-size channels as an interface between the liquid and the atmospheric pressure gas. Ions are produced by dissociation in the polar solvent and secondary ion-molecular reactions in the solution, which fills the channels of the membrane. Field extraction of the ions from the channels is stimulated by pulses of the electric discharge between the membrane and an adjacent electrode in the gas. The gas-phase ions are removed from the extraction zone by air flow and are detected by mass spectrometry. Possibilities of the membrane interface for generation of gas phase ions have been demonstrated from mass spectral investigation curried out for angiotensin II, gramicidin S and cytochrome C solutions. The current kinetics of the membrane ion source has been investigated to elucidate the mechanism of the ion extraction.
doi_str_mv 10.1016/j.elstat.2009.12.006
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1873-5738
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source Elsevier ScienceDirect Journals
subjects Atmospheric membrane ion source
Atmospheric pressure
Barometric pressure
Channels
Extraction
Field extraction of ions
Gas phases
Liquids
Membranes
Nanostructure
Track membrane
title Polymer track membranes for atmospheric pressure field extraction of ions from liquid solutions
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