The synthesis and X-ray structural characterization of mer and fac isomers of the technetium(I) nitrosyl complex [TcCl 2(NO)(PNPpr)]

The nitrosyl complex [Bu 4N][TcNOCl 4] reacts with bis[(2-diphenylphosphino)propyl]amine (PNPpr) to give mixtures of the mer or fac isomers of [TcCl 2(NO)(PNPpr)]. In acetonitrile, the mer isomer is predominantly formed. In methanol, the fac isomer of [TcCl 2(NO)(PNPpr)] precipitates cleanly however...

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Veröffentlicht in:	Inorganica Chimica Acta 2009-08, Vol.362 (10), p.3637-3640
Hauptverfasser:	Nicholson, T.L., Mahmood, A., Refosco, F., Tisato, F., Müller, P., Jones, A.G.
Format:	Artikel
Sprache:	eng
Schlagworte:	Nitrosyl Technetium(I) Tridentate
Online-Zugang:	Volltext
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