Hyperfine-Shifted 13C and 15N NMR Signals from Clostridium pasteurianum Rubredoxin: Extensive Assignments and Quantum Chemical Verification
Stable isotope-labeling methods, coupled with novel techniques for detecting fast-relaxing NMR signals, now permit detailed investigations of paramagnetic centers of metalloproteins. We have utilized these advances to carry out comprehensive assignments of the hyperfine-shifted 13C and 15N signals o...
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Veröffentlicht in: | Journal of the American Chemical Society 2009-10, Vol.131 (42), p.15555-15563 |
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Format: | Artikel |
Sprache: | eng |
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