Hyperfine-Shifted 13C and 15N NMR Signals from Clostridium pasteurianum Rubredoxin: Extensive Assignments and Quantum Chemical Verification

Stable isotope-labeling methods, coupled with novel techniques for detecting fast-relaxing NMR signals, now permit detailed investigations of paramagnetic centers of metalloproteins. We have utilized these advances to carry out comprehensive assignments of the hyperfine-shifted 13C and 15N signals o...

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Veröffentlicht in:Journal of the American Chemical Society 2009-10, Vol.131 (42), p.15555-15563
Hauptverfasser: Lin, I-Jin, Xia, Bin, King, David S, Machonkin, Timothy E, Westler, William M, Markley, John L
Format: Artikel
Sprache:eng
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