Aspartate-Catalyzed Asymmetric Epoxidation Reactions

We report enantioselective epoxidation reactions that are catalyzed by aspartic acid-containing peptides. The strategy involves the transient conversion of the aspartate carboxylic acid side chain to the corresponding peracid. Reaction of olefin with the activated catalyst regenerates that catalyst,...

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Veröffentlicht in:	Journal of the American Chemical Society 2007-07, Vol.129 (28), p.8710-8711
Hauptverfasser:	Peris, Gorka, Jakobsche, Charles E, Miller, Scott J
Format:	Artikel
Sprache:	eng
Schlagworte:	Aspartic Acid - chemistry Catalysis Epoxy Compounds - chemistry Organic Chemicals - chemical synthesis Stereoisomerism
Online-Zugang:	Volltext
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