Mechanistically Diverse Copper-, Silver-, and Gold-Catalyzed Acyloxy and Phosphatyloxy Migrations:  Efficient Synthesis of Heterocycles via Cascade Migration/Cycloisomerization Approach

A set of cycloisomerization methodologies of alkynyl ketones and imines with concurrent acyloxy, phosphatyloxy, or sulfonyloxy group migration, which allow for the efficient synthesis of multisubstituted furans and N-fused heterocycles, has been developed. Investigation of the reaction course by way...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Journal of the American Chemical Society 2007-08, Vol.129 (32), p.9868-9878
Hauptverfasser:	Schwier, Todd, Sromek, Anna W, Yap, Dahrika M. L, Chernyak, Dmitri, Gevorgyan, Vladimir
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkynes - chemistry Catalysis Copper - chemistry Cyclization Furans - chemical synthesis Gold - chemistry Imines - chemistry Isomerism Ketones - chemistry Metals - chemistry Pyrroles - chemical synthesis Silver - chemistry
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!