A three-carbon ( n+1+2) ring expansion method for the synthesis of macrocyclic enones. Application to muscone synthesis

The three-carbon ring expansion methodology commences with the preparation of a cyclic allene (C9, C11, C13), readily available from the corresponding cycloalkene via dibromocarbene addition and subsequent treatment with methyllithium. Dichloroketene addition to the cyclic allene regioselectively pr...

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Veröffentlicht in:	Tetrahedron 2008-06, Vol.64 (23), p.5497-5501
Hauptverfasser:	Erden, Ihsan, Cao, Weiguo, Price, Mary, Colton, Michael
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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