Selective Functionalization of Independently Addressed Microelectrodes by Electrochemical Activation and Deactivation of a Coupling Catalyst

We demonstrate selective functionalization of independently addressed microelectrodes by electrochemical activation and deactivation of a coupling catalyst. 1,2,3-Triazole formation between terminal acetylenes and organic azides is efficiently catalyzed by copper(I) complexes (a Sharpless “click” re...

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Veröffentlicht in:	Journal of the American Chemical Society 2006-02, Vol.128 (6), p.1794-1795
Hauptverfasser:	Devaraj, Neal K, Dinolfo, Peter H, Chidsey, Christopher E. D, Collman, James P
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Chemistry Copper - chemistry Electrochemistry Electrochemistry - methods Exact sciences and technology Ferrous Compounds - chemistry General and physical chemistry Microelectrodes Miscellaneous Oxidation-Reduction Phenanthrolines - chemistry Silver Compounds - chemistry Sodium Chloride - chemistry Study of interfaces
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