Inclusion of Methylviologen in Cucurbit[7]uril

The inclusion behavior of methylviologen (N, N′-dimethyl-4,4′-bipyridinium, MV) dication in cucurbit[7]uril (CB[7]) has been studied by using various spectroscopic and electrochemical methods. The inclusion complex of MV dication in CB[7] is stable thermodynamically and kinetically. The electrochemi...

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Veröffentlicht in:	Proceedings of the National Academy of Sciences - PNAS 2002-04, Vol.99 (8), p.5007-5011
Hauptverfasser:	Kim, Hee-Joon, Jeon, Woo Sung, Ko, Young Ho, Kim, Kimoon
Format:	Artikel
Sprache:	eng
Schlagworte:	Absorption spectra beta-Cyclodextrins Bridged-Ring Compounds - chemistry Calorimetry Cations Chemical bonds Chemistry Circular Dichroism Cyclodextrins - pharmacology Dimerization Electrochemistry Electrodes Electron transfer Electrons Enzymes Herbicides - pharmacology Imidazoles - chemistry Indium Kinetics Models, Chemical Molecules Oxidation-Reduction Paraquat - pharmacology Phosphates Physical Sciences Spectrophotometry Spectrum analysis Thermodynamics Titration Voltammetry
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