Mechanistic insights into the visible-light-driven O -arylation of carboxylic acids catalyzed by xanthine-based nickel complexes

We present a photocatalytic protocol for the O -arylation of carboxylic acids using nickel complexes bearing C8-pyridyl xanthines. Our studies suggest that the underlying mechanism operates independently of external photosensitizers. Stoichiometric experiments and crystallographic studies characteri...

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Veröffentlicht in:Chemical science (Cambridge) 2025-01
Hauptverfasser: Rodriguez-Lugo, Rafael E., Sander, Joan, Dietzmann, Simon, Rittner, Thomas, Rückel, Jannes, Landaeta, Vanessa R., Park, Jiyong, Nuernberger, Patrick, Baik, Mu-Hyun, Wolf, Robert
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Sprache:eng
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