Nanocomposites Based on Disentangled Ultra-High Molecular Weight Polyethylene: Aspects and Specifics of Solid-State Processing
The stages of solid-state processing of nanocomposites, based on nascent disentangled ultra-high-molecular-weight polyethylene (d-UHMWPE) reactor powders (RPs) and carbon nanoparticles (NPs) of various types, were meticulously investigated. The potential for optimizing the filler distribution throug...
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| Veröffentlicht in: | Polymers 2024-12, Vol.16 (23), p.3423 |
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| creator | Lebedev, Oleg V Tikunova, Ekaterina P Kurkin, Tikhon S Golubev, Evgeny K Ozerin, Alexander N |
| description | The stages of solid-state processing of nanocomposites, based on nascent disentangled ultra-high-molecular-weight polyethylene (d-UHMWPE) reactor powders (RPs) and carbon nanoparticles (NPs) of various types, were meticulously investigated. The potential for optimizing the filler distribution through variation of the processing parameters, and the impact of the d-UHMWPE RP and nanofiller type on the electrical conductivity of the resulting composites were discussed. The specifics of the dependences of conductivity and tensile strength on the deformation ratio for the composites, oriented under homogeneous shear conditions, were investigated. The obtained results and the results on piezoresistivity and temperature dependency of conductivity in the oriented and compacted composites demonstrated the independence of the UHMWPE matrix orientational strengthening on the filling. The interchangeability of high-temperature uniaxial deformation and deformation under homogeneous conditions for orientational strengthening and electrical conductivity changes in the preliminary oriented composite samples was confirmed. The potential for simultaneously achieving high strength and conductivity in composite tapes and the possibility of directly processing d-UHMWPE RP and NPs mixtures into oriented composite tapes were demonstrated. The overall results suggest that the studied composites may serve as a viable model system for investigating the deformational behavior of conductive networks comprising NPs of varying types and contents. |
| doi_str_mv | 10.3390/polym16233423 |
| format | Article |
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The potential for optimizing the filler distribution through variation of the processing parameters, and the impact of the d-UHMWPE RP and nanofiller type on the electrical conductivity of the resulting composites were discussed. The specifics of the dependences of conductivity and tensile strength on the deformation ratio for the composites, oriented under homogeneous shear conditions, were investigated. The obtained results and the results on piezoresistivity and temperature dependency of conductivity in the oriented and compacted composites demonstrated the independence of the UHMWPE matrix orientational strengthening on the filling. The interchangeability of high-temperature uniaxial deformation and deformation under homogeneous conditions for orientational strengthening and electrical conductivity changes in the preliminary oriented composite samples was confirmed. The potential for simultaneously achieving high strength and conductivity in composite tapes and the possibility of directly processing d-UHMWPE RP and NPs mixtures into oriented composite tapes were demonstrated. The overall results suggest that the studied composites may serve as a viable model system for investigating the deformational behavior of conductive networks comprising NPs of varying types and contents.</description><identifier>ISSN: 2073-4360</identifier><identifier>EISSN: 2073-4360</identifier><identifier>DOI: 10.3390/polym16233423</identifier><identifier>PMID: 39684168</identifier><language>eng</language><publisher>Switzerland: MDPI AG</publisher><subject>Composite materials ; Deformation ; Electric potential ; Electric properties ; Electrical conductivity ; Electrical resistivity ; Friction ; High temperature ; Hot pressing ; Mechanical properties ; Molecular weight ; Nanocomposites ; Nanoparticles ; Piezoresistivity ; Polyethylene ; Polymers ; Process parameters ; Radiation ; Solid state ; Strengthening ; Temperature dependence ; Tensile strength ; Ultra high molecular weight polyethylene</subject><ispartof>Polymers, 2024-12, Vol.16 (23), p.3423</ispartof><rights>COPYRIGHT 2024 MDPI AG</rights><rights>2024 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). 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The potential for simultaneously achieving high strength and conductivity in composite tapes and the possibility of directly processing d-UHMWPE RP and NPs mixtures into oriented composite tapes were demonstrated. The overall results suggest that the studied composites may serve as a viable model system for investigating the deformational behavior of conductive networks comprising NPs of varying types and contents.</description><subject>Composite materials</subject><subject>Deformation</subject><subject>Electric potential</subject><subject>Electric properties</subject><subject>Electrical conductivity</subject><subject>Electrical resistivity</subject><subject>Friction</subject><subject>High temperature</subject><subject>Hot pressing</subject><subject>Mechanical properties</subject><subject>Molecular weight</subject><subject>Nanocomposites</subject><subject>Nanoparticles</subject><subject>Piezoresistivity</subject><subject>Polyethylene</subject><subject>Polymers</subject><subject>Process parameters</subject><subject>Radiation</subject><subject>Solid state</subject><subject>Strengthening</subject><subject>Temperature dependence</subject><subject>Tensile strength</subject><subject>Ultra high molecular weight polyethylene</subject><issn>2073-4360</issn><issn>2073-4360</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNpdks1vFSEQwDdGY5vao1dD4sXL1mVhWdaLedZqTao2eTYeCQ-GfTQsrMCavEv_dqmvNq1wYGb4zVdmquolbk4IGZq3c3C7CbOWENqSJ9Vh2_SkpoQ1Tx_IB9VxStdNObRjDPfPqwMyME4x44fVzTfpgwrTHJLNkNAHmUCj4NFHm8Bn6UdX9CuXo6zP7bhFX4MDtTgZ0U8oekaXpQbI250DD-_QKs2gckLSa7QuojVWJRQMWgdndb3OMgO6jEFBStaPL6pnRroEx3fvUXX16ezH6Xl98f3zl9PVRa1I0-Zasp5vaK-HjhvSda2mfcd6qWFoeLFpzShnndkorjugZlCatUoSzikb5MZIclS938edl80EWpXWonRijnaScSeCtOLxj7dbMYbfAmNGKen6EuHNXYQYfi2QsphsUuCc9BCWJAguuTArkyjo6__Q67BEX_q7pSimpMWkUCd7apQOhPUmlMSqXA2TVcGDscW-4ngYOtr8raDeO6gYUopg7svHjbhdB_FoHQr_6mHP9_S_4ZM_YHSyxw</recordid><startdate>20241205</startdate><enddate>20241205</enddate><creator>Lebedev, Oleg V</creator><creator>Tikunova, Ekaterina P</creator><creator>Kurkin, Tikhon S</creator><creator>Golubev, Evgeny K</creator><creator>Ozerin, Alexander N</creator><general>MDPI AG</general><general>MDPI</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0001-7505-6090</orcidid><orcidid>https://orcid.org/0000-0001-9184-0467</orcidid><orcidid>https://orcid.org/0000-0002-9731-4721</orcidid></search><sort><creationdate>20241205</creationdate><title>Nanocomposites Based on Disentangled Ultra-High Molecular Weight Polyethylene: Aspects and Specifics of Solid-State Processing</title><author>Lebedev, Oleg V ; 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The potential for simultaneously achieving high strength and conductivity in composite tapes and the possibility of directly processing d-UHMWPE RP and NPs mixtures into oriented composite tapes were demonstrated. The overall results suggest that the studied composites may serve as a viable model system for investigating the deformational behavior of conductive networks comprising NPs of varying types and contents.</abstract><cop>Switzerland</cop><pub>MDPI AG</pub><pmid>39684168</pmid><doi>10.3390/polym16233423</doi><orcidid>https://orcid.org/0000-0001-7505-6090</orcidid><orcidid>https://orcid.org/0000-0001-9184-0467</orcidid><orcidid>https://orcid.org/0000-0002-9731-4721</orcidid><oa>free_for_read</oa></addata></record> |
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| source | Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; PubMed Central Open Access; MDPI - Multidisciplinary Digital Publishing Institute; PubMed Central |
| subjects | Composite materials Deformation Electric potential Electric properties Electrical conductivity Electrical resistivity Friction High temperature Hot pressing Mechanical properties Molecular weight Nanocomposites Nanoparticles Piezoresistivity Polyethylene Polymers Process parameters Radiation Solid state Strengthening Temperature dependence Tensile strength Ultra high molecular weight polyethylene |
| title | Nanocomposites Based on Disentangled Ultra-High Molecular Weight Polyethylene: Aspects and Specifics of Solid-State Processing |
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