Characterizing X‑Ray and Solution State Conformations for a Model Qubit System: {Cr7Ni} Ring Rotaxanes on a Mixed Metal Triangle

The synthesis of a series of [4]­rotaxanes, each consisting of three [2]­rotaxanes joined via a central {CrNi2} triangular linker, is reported. The resultant four [4]­rotaxanes were characterized by single crystal X-ray diffraction and electron paramagnetic resonance (EPR) spectroscopy. Orientation-...

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Veröffentlicht in:	Inorganic chemistry 2024-12, Vol.63 (48), p.22880-22891
Hauptverfasser:	Loci, Lubomir, Lockyer, Selena J., Bennett, Tom S., Rogers, Ciarán J., Brookfield, Adam, Timco, Grigore A., Whitehead, George F. S., Nawaz, Selina, Miller, Jack J., Winpenny, Richard E. P., Bowen, Alice M.
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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