Different Photodissociation Mechanisms in Fe(CO)5 and Cr(CO)6 Evidenced with Femtosecond Valence Photoelectron Spectroscopy and Excited-State Molecular Dynamics Simulations

Measured and calculated time-resolved photoelectron spectra and excited-state molecular dynamics simulations of photoexcited gas-phase molecules Fe­(CO)5 and Cr­(CO)6 are presented. Samples were excited with 266 nm pump pulses and probed with 23 eV photons from a femtosecond high-order harmonic gene...

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Veröffentlicht in:	The journal of physical chemistry letters 2024-11, Vol.15 (47), p.11830-11838
Hauptverfasser:	Schröder, Henning, Coates, Michael R., Jay, Raphael M., Banerjee, Ambar, Sorgenfrei, Nomi L.A.N., Weniger, Christian, Mitzner, Rolf, Föhlisch, Alexander, Odelius, Michael, Wernet, Philippe
Format:	Artikel
Sprache:	eng
Schlagworte:	Letter Physical Insights into Materials and Molecular Properties
Online-Zugang:	Volltext
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