Halogenation-induced C-N bond activation enables the synthesis of 1,2- cis C -aryl furanosides via deaminative cyclization

1,2- -Aryl furanosides are prevalent in nature and exhibit significant biological activities. The 1,2- configuration is less favorable in terms of stereoelectronic and steric effects, making the synthesis of this type of skeleton highly challenging. Traditional methods for the synthesis of 1,2- -ary...

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Veröffentlicht in:	Chemical science (Cambridge) 2024-12, Vol.16 (1), p.410-417
Hauptverfasser:	Wang, Wenbo, Wu, Jiawei, Jiang, Kaiyu, Zhou, Maochao, He, Gang
Format:	Artikel
Sprache:	eng
Schlagworte:	Amines Aromatic compounds Biological effects Chemical synthesis Chemistry Halogenation Natural products Reagents Stereoselectivity Steric effects Substitution reactions
Online-Zugang:	Volltext
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